Scientific Quarterly Journal of Geosciences

Scientific Quarterly Journal of Geosciences

Geology, mineralogy, geochemistry, and genesis of Garmab sodium sulfate deposit, East of Semnan

Document Type : Original Research Paper

Authors
Department of Petrology and Economic Geology, Faculty of Earth Sciences, Shahrood University of Technology, Shahrood, Iran
Abstract
The geological rock units in the Garmab area include the Eocene pyroclastic, lava flow, sedimentary, evaporite, and Oligocene- Miocene sedimentary-evaporite sequences. The sodium sulfate-bearing stratigraphic units include shale, siltstone, marl and gypsiferous marls with upper Eocene age, among which the dark gray shale unit has the most association with sodium sulfate. The amounts of MgO, CaO, and Na2O in the Garmab shales are higher than the North American Shale Composition (NASC), which indicates their deposition in a shallow and closed marine environment. The Garmab sodium sulfate was deposited under hot and dry climate conditions at the latitude of 25o to 40o N and the action of hydrothermal fluids related to Eocene volcanic activities reached to the basin floor through oblique-slip active faults. Based on the mineralogy of Garmab deposit (glauberite, anhydrite, gypsum, and halite), seawater brines are rich in calcium, sodium, chlorine and sulfate. The sedimentary-evaporite layers were most likely deposited in the post-rift stage and in the marginal parts of the subduction-related intracontinental basins and or in the central parts of the shallow rift basins when the basin floor was uplifted. The Garmab sodium sulfate is classified in the category of marine evaporite deposits, which was formed in a shallow intracontinental basin.
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Afshar, A., Norouzi, G.H., Moradzadeh, A., and Riahi, M.A., 2018. Application of magnetic and gravity methods to the exploration of sodium sulfate deposits, case study: Garmab mine, Semnan, Iran. Journal of Applied Geophysics, 159, 586–596. https://doi.org/10.1016/j.jappgeo.2018.10.003.
Aghanabati, A., Hamedi, A.R., Samadian, M.R., Nabavi, M.H., Alavi-Naini, M., and Shahrabi, M., 1994. Geological quadrangle of Semnan, 1:250,000 series, No. G5, Geological Survey of Iran, Tehran.
Alavi-Naini, M., 1997. Geological quadrangle of Jam, 1:100,000 series, No. 6761, Geological Survey of Iran, Tehran.
Armstrong-Altrin, J.S., and Machain-Castillo, M.L., 2016. Mineralogy, geochemistry, and radiocarbon ages of deep sea sediments from the Gulf of Mexico. Journal of South American Earth Sciences 71, 182-200. DOI:10.1016/j.jsames.2016.07.010.
Bahar-Firouzi, K., Arefipour, S., Ahmadi, A., and Sadeghi, A., 2017. Geological map and report of Kalate Abgarm (6761IIISE), scale 1:25000, Geological Survey and Mineral Exploration of Iran. (In Persian).
Berberian, M., 1983. Structural evolution of the Iranian Plateau; Contribution to the seismotectonic of Iran, Part IV: Continental deformation in the Iranian Plateau. Geological Survey of Iran, Report 52, 19-68.
Berberian, M., Ghorashi, M., Talebian, M., and Shoja-Taheri, J., 1996, Research and study of neotectonic and earthquake-fault risk in Semnan area, Geological Survey of Iran, 266 p. (In Persian).
Blackburn, W.H., Metcalf, R.V., and Ragland, P.C., 1994. Geochemical evolution of the Precambrian Old Rag granite, Virginia, USA: testing a U/Th exploration model. Chemical Geology 111, 177-206.
Brand, U., Morrison, J.O., and Campbell, I.T., 1998. Strontium in sedimentary rocks. In encyclopedia of Geochemistry, edited by Clare P. Marshall and Rhodes W. Fairbridge. Kluwer, Academic, Dordrecht, 712 pp. ISBN 0-421-75500-9.
Brewer, P.G., 1975. Minor elements in seawater. In: J.P. Riley and G. Skirrow (Editors), Chemical Oceanography, 1. Academic Press, New York, N.Y., 2nd ed., 451—489.
Eckardt, F.D., 2001. The origin of sulphates: An example of sulphur isotopic applications. Progress in Physical Geography, 25, 512–519. https://doi.org/10.1177/030913330102500403.
Eugster, H.P., 1980. Geochemistry of evaporitic lacustrine deposits. Annual Review of Earth and Planetary Sciences, 8, 35–63. https://doi.org/10.1146/annurev.ea.08.050180.000343.
Eugster, H.P., 1985. Oil shales, evaporites and ore deposits, Geochimica et Cosmoschimica, Acta, 49, 619-635. DOI:10.1016/0016-7037(85)90158-9.
Garver J.I., Royce P.R., and Smick T.A., 1996. Chromium and nickel in shale of the Taconic Foreland: a case study for the provenance of fine-grained sediments with an ultramafic source. Journal of Sedimentary Research, 66, 100–106. https://doi.org/10.1306/D42682C5-2B26-11D7-8648000102C1865D.
Girty, G.H., Ridge D.L., Knaack, C.H., Johnson, D., and AL-Riyami, R.K., 1996. Provenance and depositional setting of Paleozoic chert and argillite Sierra Nevada, California. Journal of Sedimentary Research 66, 107-118.
Golonka, J., 2004. Plate tectonic evolution of the southern margin of Eurasia in the Mesozoic and Cenozoic. Tectonophysics, 381 (1-4), 235-273.  https://doi.org/10.1016/j.tecto.2002.06.004.
Gromet, L.P., Dymek, R.F., Haskin, L.A., and Korotev, R.L., 1984. The North American shale composite: Its compilation, major and trace element characteristics. Geochimica et Cosmochimica Acta,48,2469-2482. https://doi.org/10.1016/0016-7037(84)90298-9.
Gu, A., and Eastoe, C.J., 2021. The origins of sulfate in Cenozoic non-marine evaporites in the basin and range province, Southwestern North America. Geosciences, 11 (11), 455. https://doi.org/10.3390/geosciences11110455.
Hardie, L.A., and Eugster, H.P., 1970. The evolution of closed-basin brines. Mineralogical Society America Special Paper 3, 273–290.
Hayashi, K.I., Fujisawa, H., Holland, H.D., and Ohmoto, H., 1997. Geochemistry of ∼1.9 Ga sedimentary rocks from northeastern Labrador, Canada. Geochimica et Cosmochimica Acta 61, 4115–4137. https://doi.org/10.1016/S0016-7037(97)00214-7.
Henderson, P., 1984. Rare earth element geochemistry. Elsevier, New York, 510 p.
Khalili, M., and Torabi, H., 2003. The exploration of sodium-sulphate in Aran playa, Kashan, central Iran. Carbonates and Evaporites, 18, 120–124. https://doi.org/10.1007/BF03176233.
Liu, C.L., Jiao, P.C., Wang, M.L., 2007. Sedimentation of glauberite and its effect on potash deposits formation in Lop Nur Salt Lake, Xinjiang, China. Mineral Deposits 26 (3), 322–329. 10.16111/j.0258-7106.2007.03.009.
Mao, L.J., Mo, D.W., Yang, J.H., Guo, Y.Y., and Lv, H.Y., 2014. Rare earth elements geochemistry in surface floodplain sediments from the Xiangjiang River, middle reach of Changjiang River, China. Quaternary International, 336, 80-88. DOI:10.1016/j.quaint.2014.01.052.
Mees, F., 1998. The alteration of glauberite in lacustrine deposits of the Taoudenni-Agorott basin, northern Mali. Sedimentary Geology, 117, 193–205. DOI:10.1016/S0037-0738(98)00042-6.
Mostafaie, K., and Ramazi, H.R., 2015. Application of electrical resistivity method in sodium sulfate deposits exploration, case study: Garmab, Iran. Journal of Biodiversity and Environmental Sciences (JBES), 6 (2), 479-487. https://innspub.net/application-of-electrical-resistivity-method-in-sodium-sulfate-deposits-exploration-case-study-garmab-iran/.
Oni, S., Olatunji, A., and Ehinola, O., 2014. Determination of provenance and tectonic settings of Niger Delta clastic facies using well-Y, Onshore Delta State, Nigeria. Journal of Geochemistry, 4, 1-13. https://doi.org/10.1155/2014/960139.
Rahimpour-Bonab, H., and Abdi, L., 2012. Sedimentology and origin of Meyghan lake/playa deposits in Sanandaj-Sirjan zone, Iran. Carbonates and Evaporites, 27, 375–393. DOI:10.1007/s13146-012-0119-0.
Safai, M., and Ghalamghash, J., 2011. Description of Semnan 1:250,000 geological map, Department of Geology and Mineral Exploration of Semnan Province, 79 p. (In Persian).
Shabanian, A., Azghandi, M., and Salmanlou, A., 2015. Structural geology report of Garmab sodium sulfate mine, Amlah Mining Company of Iran, internal and unpublished report, 25 p. (In Persian).
Sheikholeslami, M.R., Javadi, H.R., Asadi Sarshar, M., Aghahosseini, A., Kouhpeima, M., and Vahdati Daneshmand, B., 2013. Iran Faults Encyclopedia, Geological Survey of Iran, 558 p. (In Persian).
Sonnenfeld, P., 2000. The evolution of marine evaporites. In: Geertman RM (ed.) 8th World Salt Symposium, 1, 67–172. Amsterdam: Elsevier.
Warren, J.K., 2010. Evaporites through time: Tectonic, climatic and eustatic controls in marine and nonmarine deposits. Earth-Science Reviews, 98(3), 217-268. https://doi.org/10.1016/j.earscirev.2009.11.004.
Warren, J.K., 2016. Evaporites: A Geological Compendium. London, Springer, 1822 p. DOI:10.1007/978-3-319-39193-9_100-1.
Wei, D.Y., 2001. On glauberite deposits in China. Geology of Chemical Minerals 23 (2), 75–82 (In Chinese with English abstract).
Whitney, D.L., and Evans B.W., 2010. Abbreviations for names of rock-forming minerals. American Mineralogist, 95, 185-187.
Wignall, P.B., and Twitchett, R.J., 1996. Oceanic anoxic and the end Permian mass extinction. Science 272, 1155-1158. DOI: 10.1126/science.272.5265.1155.
Yu, X.C., Wang, C.L., Liu, C.L., Zhang, Z.C., Xu, H.M., Huang, H., Xie, T.X., Li, H.N., and Liu, J.L., 2015. Sedimentary characteristics and depositional model of a Paleocene–Eocene Salt Lake in the Jiangling Depression, China. Chinese Journal of Oceanology and Limnology, 33, 1426–1435. DOI:10.1007/s00343-015-4375-4.