Scientific Quarterly Journal of Geosciences

Scientific Quarterly Journal of Geosciences

Mineralogical Specifications, Metasomatic Alteration and Conditions of Fe-Skarn Formation at Pahnavar, East of Siahrood, East-Azarbaidjan, Iran

Document Type : Original Research Paper

Authors
1 Geology Department, Natural Science Faculty, Tabriz University, Tabriz, Iran
2 Research Institute for Fundamental Sciences (RIFS), Tabriz Iran
Abstract
Pahnavar skarn, located in the east of Siahrood, is a typical magnetite-rich skarn developed along the contact of Qolan granitoid (quartz diorite) I-type intrusive body (Oligo-Miocene) with carbonate (principally limestone) rocks. Field evidenceand mineralogical study show that Pahnavar skarn is of calcic-type and includes two distinct zones: 1) endoskarn and 2) exoskarn. Exoskarn is the major skarn zone and by itself includes two separate zones: a) garnet skarn in igneous contact side and b) epidote skarn in parts farther from the contact. Two general stages of skarnification were recognized in Pahnavar: 1) prograde and 2) retrograde. Prograde stage was developed within the temperature ranges of 470-550 ºC and includes two discrete stages: a) isochemical formation of hornfelsic skarnoid (bimetasomatic) and recrystallized limestone (marble) and b) formation of metasomatic skarn during which a series of medium to coarse-grained anhydrous calc-silicates were developed. Retrograde stage commenced at temperatures <470 ºC and includes two distinct stages: 1) early retrograde stage during which anhydrous calc-silicate assemblages (formed during prograde stage) were replaced by a series of hydrous calc-silicates (epidote, tremolite-actinolite), silicates (quartz), carbonates (calcite), and opaques (magnetite, hematite, and pyrite). Magnetite was principally developed during this stage. 2) Late retrograde stage during which most of minerals formed during previous stages were altered into a series of fine-grained aggregates of chlorite, calcite, quartz, hematite, and clay minerals.
Keywords

Subjects


Bazin, D., Hubner, H., 1969- Copper deposits of Iran. Geological Survey of Iran, Rep. No. 13, 232p.
Berman, R.G., Brown, T.H., Greenwood, H. J., 1985- An internally consistent thermodynamic data base for minerals in the system Na2O-K2O-CaO-MgO-FeO-SiO2-Al2O3-Fe2O3-TiO2-H2O-CO2. Atomic Energy of Canada Technical Report TR-337, 62 p.
Burnham, C.W., 1979- Magmas and hydrothermal fluids, in Barens, H.L. ed., Geochemistry of hydrothermal ore deposits: New York, John Wiley, pp. 71-136.
Chappell, B. W.,White, A. J. R., 1984- I- and S-type granites in the Bachlan Fold Belt, Southeastern Australia. In: Kegin, X. & Guanchi, T. (editors), Geology of granites and their metallogenic relations, Science Press, pp. 87-101.
Ciobanu, C.L.,  Cock, N. J., 2004- Skarn textures and a case study: the Ocna de Fier-Dognecea orefield, Banat, Romania. Ore Geology Review, vol 24, pp. 315-370.
Deer, W. A., Howie, R. A., Zussman, J., 1992- An introduction to the rock forming minerals. Second edition, Longman Scientific and Technical, 696 p.
Eftekhar-Nazhad, J., 1989- Geological Map of Tabriz-Poldasht, 1:250000, Geol. Surv. Of Iran, No. B1 & B2.
Einaudi, M. T., 1982- General features and origin of skarns associated with porphyry copper plutons. Advances in geology of porphyry copper deposits. S. W. North America, pp. 185-209.
Irvine, T. N.,  Baragar, W. R. A., 1971- A guide to the chemical classification of the common volcanic rocks. Canadian Journal of  Earth Science, vol.8, pp. 523-548.
Jamtveit, B., Wolgelius, R. A. & Fraser, D. G., 1993- Zoning patterns of skarn garnets: Records of hydrothermal system evolution. Geology, 21, pp. 113-116.
Kretz, R., 1983-Symbols for rock-forming minerals. American Mineralogist, 68, p. 277-279.
Le Maitre, R.W., 1976- Some problems of the projection of chemical data into mineralogical classification. Contribution to Mineralogy and Petrology, vol 56, pp. 181-189.
Le Maitre, R.W., Bateman, P., Dudek, A., Keller, J., Lameyre, M. J., Sabine, P. A., Schmind, R., Sorensen, H., Streckeisen, A., Wooley, A. R. & Zanettin, B., 1989-A classification of igneous rocks and glossary of terme. Blackwell, Oxford.
Lentz, D.R., Walker, J. A. & Stirling, J. A. R., 1995- Millistream Cu-Fe skarn deposit: an example of a Cu-bearing magnetite-rich skarn system in northern New Brunswick. Explor. Mining Geol., Vol 4, No. 1, pp. 15-31.
Manier,P.D., Piccoli,P. M.,1989-Tectonic discrimination of granitoids.Geological Society of America Bulletin,101,pp.635-643
Muller,D., Rock, N.M.S., Groves,D.I.,1992- Geochemical discrimination between shoshonitic and potassic volcanic rocks from different tectonic settings: a pilot study. Mineralogy and  Petrology., vol 46, pp. 259-289.
Pearce, J. A., 1996- Source and setting of granitic rocks. Episode, vol. 19, pp. 120-125.
Perkins, E. H., Brown, T. H. & Berman, R.G., 1986-PTX-SYSTEM: three programs for calculation of pressure-temperature-composition phase diagrams. Computers and Geoscience, 12, p. 749-755.
Stephens,W.E., Halliday, A.L., 1984- Geological contrasts between late Caledonian granitoid plutons of Northern, Central and Southern Scotland. Royal Society of Edinburgh Transactions, Earth Sciences, vol 75, pp. 259-274.