Geological Environment and Engineering
Neda Khajooee; Sourosh Modabberi; Behnoush Khosh manesh Zadeh; Fatemeh Razavian
Abstract
Population growth and increasing urbanization expose city dwellers to higher degrees of urban pollutants, especially when they spend long time in enclosed environments with inadequate ventilation. This study is the first research on inorganic pollutants in indoor dust particles of Tehran city, which ...
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Population growth and increasing urbanization expose city dwellers to higher degrees of urban pollutants, especially when they spend long time in enclosed environments with inadequate ventilation. This study is the first research on inorganic pollutants in indoor dust particles of Tehran city, which applies geochemical indices to estimate the intensity of dust pollution by potentially harmful elements. A number of 31 indoor dust samples were passively collected from inside the residential and office buildings in the central and densely populated districts of the city and were analyzed by ICP-Ms at the Universitat Rovira i Virgili, Tarragona, Spain. Single geochemical indices of the Contamination Factor, Geoaccumulation Index, Enrichment Factor, and cumulative indices of Pollution Load and Potential Ecological Risk Indices were calculated. The results of elemental analysis showed that the concentration of arsenic, cadmium, copper, mercury, lead and zinc in Tehran indoor dust is higher than that in some cities in the world. On the other hand, cobalt, chromium, nickel and vanadium present low concentrations in the analyzed indoor dust samples. This result was confirmed by the cumulative indices as well as the contamination factor. In contrast, some other factors showed a low to medium degree of pollution for the above-mentioned elements. Based on the obtained concentration of elements in the dust samples, it can be argued that the geochemical indices indicating low to moderate pollution are not applicable and trustable in the current study.
Petrology
Niloofar Nayebi; Dariush Esmaeily; Soroush Modabberi; Ryuichi Shinjo
Abstract
Anomaly 21A, as a part of Bafq iron-apatite ore metallogenic district, is located in Central Iran, and encompasses wide spectrume of igneous, sedimentary and metamorphic rocks. The igneous rocks that show narrow geochemical variations and dominantly plot in the monzonite to monzodiorite fields, are ...
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Anomaly 21A, as a part of Bafq iron-apatite ore metallogenic district, is located in Central Iran, and encompasses wide spectrume of igneous, sedimentary and metamorphic rocks. The igneous rocks that show narrow geochemical variations and dominantly plot in the monzonite to monzodiorite fields, are plotted in the calc-alkaline and high-K calc-alkaline affinities. Geochemical data are characterized by enrichment LILE and LREE as compare to HFSE and HREE, respectively, and depletions in Nb-Ta-Ti imply the mantle-derived melts modified by subduction components. The isotopic signatures of Anomaly 21A samples, e.g., (87Sr/86Sr)i, εNd(t)=, imply the dominant mantle signature. Their initial Pb isotopic composition of study rocks are 18.87 to 20.32 for (206Pb/204Pb), 15.72 to 15.84 for (207Pb/204Pb), and 40.74 to 42.32 for (208Pb/204Pb). The isotopic modellings show less than 4% incorporation of melt-derived subducted sediment into the mantle wedge or variable degrees of contamination by upper continental crust. We suggest partial melting of a sub-arc mantle melt that has been metasomatized by slab-derived sediments and interacted with continental crust en-route the shallower surface as the premise of the geodynamic of Central Iran.
Petrology
Niloofar Nayebi; Dariush Esmaeily; Sourosh Modabberi; Ryuichi Shinjo; Reza Deevsalar; Bernd Lehmann
Abstract
Sr-Nd-Pb isotopes and whole-rock geochemical analyses were carried out on plutonic rocks of the Chadormalu district to constrain the magmatic history of the Cadomian orogeny of the northern Gondwana margin during Late Precambrian–Early Paleozoic times. Despite the similarities in the geochemical ...
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Sr-Nd-Pb isotopes and whole-rock geochemical analyses were carried out on plutonic rocks of the Chadormalu district to constrain the magmatic history of the Cadomian orogeny of the northern Gondwana margin during Late Precambrian–Early Paleozoic times. Despite the similarities in the geochemical data, i.e., calc-alkaline affinity, enrichment in large ion lithophile elements (e.g., Rb, Ba, K, and Cs), and depletion in high field strength elements, e.g., Nb, Ta, P, Ti, and rare earth element patterns, bulk rock Sr-Nd isotope data rull out the co-magmatic nature of investigated basic (gabbro) and felsic (granite) magmas. Sr-Nd isotopic data (e.g., ɛNd(t)= -3.6 to +1.8) along with rather high (207Pb/206Pb)t attest to the crust-dominant, and mantle-derived melts for the granitoids and gabbros, respectively. The investigated zircons yielded the older ages for the gabbroic samples. The extensional tectonic regime is followed by slab retreat or delamination brought flare-up of the oldest arc-related igneous rocks and interacted with Cadomian basement to form the investigated granitoid melts. The gabbroic rocks show geochemical and isotopic disruption and elevation of L-MREE/HREE ratios on the chondrite-normalized rare earth element (REE) patterns; interpreting the evidences of mantle heterogeneity and interaction with Paleoproterozoic basement.
Economic Geology
Sahar Tarabi; Mohamad Hashem Emami; Sourosh Modaberi; Seyed Jamal Shaykh Zakariaee
Abstract
Momen-abad area, in the southeast of Birjand and the northeast of Sarbisheh, is located in the Sistan-Zemestan zone. Based on the field studies, petrography, geochemical (XRF) and X-ray diffraction (XRD) in two volcanic sequences, the alteration conditions in the area have been investigated. According ...
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Momen-abad area, in the southeast of Birjand and the northeast of Sarbisheh, is located in the Sistan-Zemestan zone. Based on the field studies, petrography, geochemical (XRF) and X-ray diffraction (XRD) in two volcanic sequences, the alteration conditions in the area have been investigated. According to mineralogy and chemical studies, bentonites are sodium-calcium and heterogeneous. Mineralogy findings indicate that smectite minerals, cristobalite and quartz, alkaline feldspars (albite and anorthite and sanidine), gypsum, calcite, hematite, holandite, klinoptiolite, kaolinite, ileite, and halite minerals form bentonites. In the first sequence, the effects of argillic and iron oxide alterations and in the second sequence, the effects of alteration of argillic, carbonate, chlorite, calcite, albite, silicification and iron oxide are found. Altered units which are related to the second sequence in four layers include Rhyolytic perlites of the vein, masses, lenses; white bentonites and green; Rhyodacite and dacite with the effects of alteration of devitrification, and the alteration of perlite to bentonite, advanced argillic and silicification. In addition, the composition textures of lava-pyroclastic, devitrification and the alteration of perlite to bentonite due to diagenetic alteration are found out. Glass argillization and feldspars in volcanic units, and the alteration of plagioclase to albite + sericit, biotite to chlorite, stone to quartz, calcite, zeolite and chlorite in perlites, iron oxide veins and red unit are found out in the sequences. Moreover, the change color of bentonite in the region related to alteration hydrothermal, and the presence of fluids and iron-magnesium-rich solutions are obvious in these sequences.
Geological Environment and Engineering
Abbas Fallah; Soroush Modabberi; Alireza Sayyareh; amir ali Tabakh shabani
Abstract
For study the effects of traffic and urban pollution on heavy metals concentration, 40 soil samples were collected in green areas of Karaj city with different uses and 5 samples as geochemical background were collected from unpolluted areas and margins of the city. The samples after preparation were ...
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For study the effects of traffic and urban pollution on heavy metals concentration, 40 soil samples were collected in green areas of Karaj city with different uses and 5 samples as geochemical background were collected from unpolluted areas and margins of the city. The samples after preparation were analyzed by ICP-OES method. Statistical data were analyzed by SPSS (version 21) software. Relation of elements and pollution indexes determined for noticeable elements in karaj city. The Statistical analysis indicate that the distribution of metal such as: Cd,Cr,Cu,Ni and Zn in soil of Karaj city are similar to each other and often in the central part of Karaj city( Jahanshaher garden , Family park) Compared to other regions is more. Heavy metals in farmland soil are lower than other lands (garden, park). These findings are matching with the results reported by other researchers (from other regions of world). As, S and Zn have different distribution than other listed heavy metals. The Mean value of Zn, P, Ni, Cu, Cr, Co and Cd in the central part of Karaj city is more than other regions. PI value in the Karaj city soil for various heavy metals are respectively as: As>S>P>Zn>Pb>Cu>Ni, Cr>Cd The heavy metals pollution index for Karaj is 1.75, which is one of the moderate pollution soils.
S. Shariati; S. A. Aghanabati; S. R. Mousavi Harami; S. Modabberi; M. H. Adabi
Abstract
Angouran Lead and Zinc Mining deposit is one of the biggest Lead and Zinc deposits of Middle East and one of five great mines of Iran according to the article of categorization of the mines of Iran. In addition to the diverse metal and non-metal mines, there are many industries and factories in this ...
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Angouran Lead and Zinc Mining deposit is one of the biggest Lead and Zinc deposits of Middle East and one of five great mines of Iran according to the article of categorization of the mines of Iran. In addition to the diverse metal and non-metal mines, there are many industries and factories in this region which most of them were active and are as conversion industries of Zinc soil into the Concentrate or as factoring of Lead and Zinc Bar. The realized studies demonstrate that due to activation of existent industries in that region, the rate of some elements are in unusual level and show some fundamental environmental abnormalities. The environment of the region is mostly influenced by the accumulation of wastes and residues dispossessed as cake in the borders of the rivers and canals and open lands. These Cakes which as a matter of fact are the residues of proceeding of the flotation and melting the Lead and Zinc and the process of Concentrate factoring, may have lost the great amount of their Lead and Zinc in the industrial point of view, but as an environment view, those have a lot of Lead and Zinc many times more than allowed limits which are potentially toxic. At the other hand, by reduction of these elements, the densities of other elements are increasing. This means intensive effects which in this paper are going to be surveyed. The rates of these elements in some samples are reported exceeding to 10,000 ppm Lead and Zinc and Nickel and also 8,000 ppm Arsenic and 4,000 Cadmium. The studies also demonstrate that waste pool or the pools of residues are one of the most fundamental causes of dangers for the environment of the region. The rate of 200,000 ppm of Zinc and sometimes 2000 ppm of Lead and 20,000 ppm Nickel, also tha rate of some hundreds ppm of arsenic and even 200,000 ppm of Cadmium in the water and water deposits of the region are some of those dangers. The most of these abnormalities are seen in the sediments and water of the region, however the agricultural grounds are also influenced by these pollutions and are included some major abnormalities in term of the environment. This paper will exclusively review the allowed rate of the elements of Lead, Zinc, Cadmium, and Arsenic and survey the principal manners of access of these elements to the environment of region and also try to present some solution for the control and reduction of these rates.
Y. Rahimsouri; A. Yaghubpur; S. Modabberi
Abstract
The results of physicochemical parameters (pH, Eh, EC, TDS, TH, TA, T, and Salinity) and chemical analyses of the springs and drinking water samples of the study area indicate obvious variation compared to each other. Based on these results, the minimum pH and maximum of TDS, EC, salinity, total hardness(TH), ...
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The results of physicochemical parameters (pH, Eh, EC, TDS, TH, TA, T, and Salinity) and chemical analyses of the springs and drinking water samples of the study area indicate obvious variation compared to each other. Based on these results, the minimum pH and maximum of TDS, EC, salinity, total hardness(TH), total alkalinity(TA) parameters and cations and anions, major and trace elements (especially As and Sb) concentrations in spring water samples belong to spring Aq.D1-1(located downstream of Aq-Darreh Bala abandoned antimony mine) and spring Sp.5 (downstream of tailing dams of Aq-Darreh Au mineral processing unit) samples, and the drinking water samples of the Aq-Darreh Paeen village ( spring D.W.P). The Aq-Darreh Paeen drinking water, supplied from the spring near the village, outpoured from the mineralized travertine. Compare to the international standards, main cations and anions concentrations and physicochemical parameters values (exception total hardness) of the springs and drinking water samples are located in permissible ranges. While, Aq-D1-1, Sp.5 and W.D.P springs water samples are polluted regarding to total hardness value and As concentration. Based on the geological map of the study area and location of the all spring water samples (except spring Sp.5), it can be concluded that the chemical composition of the bed rocks around the springs had the main role in controlling the water quality, and the main cause of Sp.5 water spring contamination is polluted waters leaked from the tailing dams of Aq-Darreh Au mineral processing unit.
