Economic Geology
masoumeh Norouzi; Ali Abedini; Ali Asghar Calagari; Fatemeh Kangarani Farahani
Abstract
The kaolin occurrence in the Abolhasani-Zereshkouh area (south of Shahroud, northeast of Iran) is a product of alteration of Eocene andesitic rocks. With attention to mineralogical studies, kaolinite, quartz, chlorite, montmorillonite, illite, rutile, calcite, orthoclase, albite, vermiculite, palygorskite, ...
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The kaolin occurrence in the Abolhasani-Zereshkouh area (south of Shahroud, northeast of Iran) is a product of alteration of Eocene andesitic rocks. With attention to mineralogical studies, kaolinite, quartz, chlorite, montmorillonite, illite, rutile, calcite, orthoclase, albite, vermiculite, palygorskite, jarosite, and hematite are the mineral assemblege of this alteration occurrence. Calculations of mass balance of elements with assuming Zr as monitor immobile element show that elements such as Si, Fe, Mg, Na, K, Ti, Cr, Ba, Be, Co, Cs, Rb, Sn, U, V, W, Ni and REE were partially depleted and elements such as Hf, Zn and Cd enriched during the kaolinitization processes of andesitic rocks. Other elements including Al, Ca, P, Mn, Ga, Nb, Sr, Ta, Th, Y, Cu, Pb and Tl were undergone both leaching and fixation processes. The mass decrease of Si, Fe, K, Rb, Cs and Ba reveals destruction of plagioclase and hornblende by highly acidic hydrothermal fluids. The presence of two abnormal decreasing and increasing trends for the elements Al, Ga, P, Nb, Ta, and Y can be attributed to the low pH of the altering fluids, the high water-to-rock ratio and the abundance of complexing legands.
M Norouzi; M. Lotfi; M. H. Emami; H. Jamali; A. Abedini
Abstract
Mesgarabad area is located in ~10 km southeast of Tehran, the Central- Alborz structural zone (CASZ) of Iran. The rock units exposed in the area consist of Eocene volcanics, volcano-sedimentary and sedimentary rocks intruded by post upper Eocene granodiorite to quartz monzo-diorite. These subvolcanic ...
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Mesgarabad area is located in ~10 km southeast of Tehran, the Central- Alborz structural zone (CASZ) of Iran. The rock units exposed in the area consist of Eocene volcanics, volcano-sedimentary and sedimentary rocks intruded by post upper Eocene granodiorite to quartz monzo-diorite. These subvolcanic intrusive bodies show porphyroid to microgranular textures and have calc-alkaline magmatic nature. These bodies produced hydrothermal fluids causing extensive alteration zones developed along the Se-Darreh-e-Bozorg strike-slip fault. The effects of hydrothermal fluids on the entire Eocene rock units and subvolcanic intrusive bodies are remarkable. The main alterations are silicification, sericitization, chloritization, epidotizaton, actinolitization, argillization, carbonatization, and alunitization-jarositization, which provided suitable physico-chemical conditions for ore-mineralization. The penetration of subvolcanic intrusive bodies into the Eocene volcanics, volcano-sedimentary and sedimentary rocks brought about skarn mineralization and epithermal barite veins. Microscopic studies and advanced analysis showed that the principal mineral phases in the epithermal zones are magnetite, pyrite, chalcopyrite, bornite, chalcocite, barite, Cu+Sn+Fe alloy, hematite, psilomelane, jacobsite, martite, geothite, and lepidochrosite. The skarnification processes occurred at two distinct stages, (1) progressive and (2) retrogressive. The pyrometasomatic anhydrous minerals such as andradite-grossularite formed during progressive stage and the hydrous minerals like epidote, chlorite, tremolite- actinolite, calcite, quartz, pyrite, chalcopyrite and chalcocite were developed during retrogressive stage. Fluid inclusion studies on primary aqueous inclusions trapped in barite crystals revealed fluid that mixing of two fluids having different physico-chemical conditions played an important role for ore deposition.
