A. Abedini; A. Oroji; A. A. Calagari
Abstract
Thekaolinizedzonesof the Goorgoor area (north of Takab, West-Azarbaidjan province) are alteration products of andesitic rocks of Miocene age in northwest of Iran. Based on the mineralogical studies, kaolinite, quartz, jarosite, montmorillonite, albite, muscovite-illite, anatase, chlorite, orthoclase, ...
Read More
Thekaolinizedzonesof the Goorgoor area (north of Takab, West-Azarbaidjan province) are alteration products of andesitic rocks of Miocene age in northwest of Iran. Based on the mineralogical studies, kaolinite, quartz, jarosite, montmorillonite, albite, muscovite-illite, anatase, chlorite, orthoclase, calcite, goethite and hematite are mineral phases in these zones. The silicic veins existing within these zones include metallic minerals such as pyrite, chalcopyrite, galena, sphalerite, bornonite, and stibnite. The mass change calculations of rare earth elements (REEs), with assumption of Sc as a monitor immobile element, reveal that development of kaolinization processes were accompanied by enrichment-depletion of La-Nd and depletion of Sm-Lu. Geochemical analyses show that the degree of differentiation of Al from Fe and destruction of zircon by hydrothermal fluids are the most important controlling factors for variation of Eu (0.84-1.06) and Ce (0.83-0.93) anomalies in these zones, respectively. Positive and strong correlations of (La/Lu)N and (LREEs/HREEs)N values with components such as P, S, LOI, and Sr establish the effective role of hypogene solutions in progression of kaolinization processes. The combination of the obtained results from mineralogical and geochemical investigations suggest that changes in chemistry of altering solutions (e.g., pH and Eh) and diversity in type of fixing minerals are two key factors affecting differentiation and distribution of REEs in the kaolinizedzones at Goorgoor.
A Zahedi; M Boomeri
Abstract
The Panah-Kuh skarn is situated in 50km NW of Taft City in Yazd province. Inrtusion of granodioritic stock into the calcareous-dolomitic rocks of Permian Jamal Formation led to formation of calcic and magnesian skarns. The REE patterns of skarns and its forming garnets show Eu/Eu* and Ce/Ce*ratios increase ...
Read More
The Panah-Kuh skarn is situated in 50km NW of Taft City in Yazd province. Inrtusion of granodioritic stock into the calcareous-dolomitic rocks of Permian Jamal Formation led to formation of calcic and magnesian skarns. The REE patterns of skarns and its forming garnets show Eu/Eu* and Ce/Ce*ratios increase with increasing of ∑REE, implying that skarn forming fluids were dominantly of magmatic origin, whereas (Pr/Yb)cn ratio decrease almost with increasing of ∑REE that implying the magmatic fluids granitoid-derived had not much REE during the Panah-Kuh skarn formation. Based on the fluid inclusion data from garnet, fluid temperature and salinity in the prograde stage vary between 308-380oC and 12.6-23.8 wt.% NaCl equivalent, respectively. Inclusion fluids in the calcite had lower temperature (T<280°C) and fluid salinity decline to 3.5 wt.% NaCl equivalent. Mixing and dilution of early magmatic fluids with external fluids (e.g., meteoric waters) caused a decrease in fluid temperature and salinity in latest stage of the skarn formation. Therefore, both REEs and fluid inclusions data suggest the dominant role of magmatic water in the formation of Panah-Kuh skarn.