Document Type : Original Research Paper

Authors

1 Geology Faculty, College of Science, Tehran University, Tehran , Iran

2 Geology Department, Faculty of Natural Sciences, Tabriz University, Tabriz , Iran.

3 Geology Department, Faculty of Sciences, Urmia University, Urmia, Iran.

Abstract

Boket residual horizon is located in ~15 km northeast of Ajabshir, East-Azarbaijan province. This horizon was developed as stratiform lenses along the contact of Ruteh (middle-upper Permian) and Elika (Triassic) carbonate formations. The ores within this horizon display pelitomorphic, micro-granular, micro-ooidic, pseudo-porphyritic, ooidic, pisoidic, pseudo-breccia, and nodular textures. Based on geochemical data, the ores within this horizon are divided into five types, (1) ferritic  laterite, (2) bauxitic laterite, (3) kaolinitic laterite, (4) ferritic kaolinite, and (5) laterite. Comparison of distribution patterns of elements across a selected profile indicates the effective role of Al and Ti in distributing and concentrating of Zr, Ga, Nb, Th, V, and HREEs within the ores. Incorporation of data obtained from petrographical and geochemical studies shows that the ores have authigenic origin. Furthermore, factors such as chemical variations of weathering solutions, fixation in neomorphic phases, existing in resistant minerals, heterogeneity of protolith, differences in the degree of weathering intensity, and adsorption processes coupled with weak drainage, diagenesis, dynamic pressures, and fluctuation of underground water table played crucial roles in distribution and development of ores within this horizon. The most notable geochemical characteristics of the ores (except in kaolinitic laterite) is the greater mobility of LREEs relative to HREEs during weathering processes. This abnormal behavior within the horizon could be related to factors such as differences in stability of primary minerals containing REEs, the pH variation (from 6.7 to 7.8) of weathering solutions, and moderate degree of evolution of the profile.

Keywords

References
Aleva, G. J. J., 1994- Laterites: Concepts, geology, morphology and chemistry. ISIRC, Wageningen, 169p.
Bardossy, G., 1982- Karst Bauxites. Elsevier Scientific, Amsterdam, 441p.
Beyala, V. K. K., Onana, V. L., Priso, E. N. E., Parisot, J. & Ekodeck, G. E., 2009- Behaviour of REE and mass balance calculations in a lateritic profile over chlorite schists in South Cameroon. Chemie der Erde - Geochemistry 69, 61-73.
Boulange, B., 1984- Les formation bauxitigues lateriques de Cote d Ivoire. Travaux et Doduments ORSTOM , Paris 175, 341p.
Braun, J. J., Pagel, M., Muller, J. P., Bilong, P., Michard, A. & Guillet, B., 1990- Ce anomalies in lateritic profiles. Geochimica et Cosmochimica Acta 54, 781-795.
Calagari, A. A. & Abedini, A., 2007- Geochemical investigations on Permo-Triassic bauxite deposit at Kanisheeteh, east of Bukan, Iran. Journal of Geochemical  Exploration 94, 1-18.
Calagari, A. A., Kangrani, F. & Abedini, A., 2010- Geochemistry of major, trace and rare earth elements in Biglar Permo-Triassic bauxite deposit, northwest of Abgarm, Ghazvin province. Journal of Sciences 21, 225-236.
Fernandez-Caliani, J. & Cantano, M., 2010- Intensive kaolinization during a lateritic weathering event in southwest Spain mineralogical and geochemical inferences from a relict paleosol. Catena 80, 23-33.
Henderson, P., 1984- Rare Earth Element Geochemistry. Elsevier, Amsterdam, 510p.
Hudson, E. A., Terminello, L. J., Viani, B. E., Denecke, M., Reich, T. & Allen, P. G., 1999- The structure of U6+ sorption complexes on vermiculite and hydrobiotite. Clays and Clay Minerals 47, 439-457.
Karadag, M., Kupeli, S., Arik, F., Ayhan, A., Zedef, V. & Doyen, A., 2009- Rare earth element (REE) geochemistry and genetic implications of the Mortas bauxite deposit (Seydisehir/Konya-southern Turkey. Chemie der Erde- Geochemistry 69, 143-159. 
 Laskou, M. & Economou-Eliopoulos, M., 2007- The role of microorganisms on the mineralogical and geochemical characteristics of the Parnassos-Ghiona bauxite deposits, Greece. Journal of Geochemical Exploration 93, 67-77.
Ma, J., Wei, G., Xu, Y., Long, W., and Sun, W., 2007. Mobilization and re-distribution of major and trace elements during extreme weathering of basalt in Hainan Island, South China. Geochimica et Cosmochimica Acta 71, 3223-3237.
MacLean, W. H., Bonavia, F. F. & Sanna, G., 1997- Argillite debris converted to bauxite during karst weathering: evidence from immobile element geochemistry at the Olmedo deposit, Sardinia, Mineralium Deposita 32, 607-616.
Mameli, P., Mongelli, G., Oggiano, G. & Dinelli, E., 2007- Geological, geochemical and mineralogical features of some bauxite deposits from Nurra (western Sardinia, Italy): Insights on conditions of formation and parental affinity. International Journal of Earth Sciences 96, 887-902.
Meinhold, G., 2010- Rutile and its applications in earth sciences. Eatrh Scince Reviews 102, 1-28.
     Marques, J. J., Schulze, D. G., Curi, N., and Mertzman, S. A., 2004. Trace element geochemistry in Brazilian Cerrado soils. Geoderma 121, 31-43.
Mordberg, L. E., 1993- Patterns of distribution and behavior of trace elements in bauxites. Chemical Geology 107, 241-244.
Mordberg, L. E., 1999- Geochemical evolution of a Devonian diaspore-crandallite- svanbergite bearing weathering profile in the Middle Timan, Russia. Journal of Geochemical Exploration 66, 353-361.
Muggler, C. C., 1998- Polygenetic oxisols on Tertiary surfaces, Minas Gerais Brazil. Ph.D thesis. Wageningen university., Netherlands.
Mutakyahwa, M. K. D., Ikingura, J. R. & Mruma, A. H., 2003- Geology and geochemistry of bauxite deposits in Lushoto district, Usambara Mountains, Tanzania. Journal of African Earth Sciences 36, 357-369.
Newman, A. D. C., 1987- Chemistry of clays and clay minerals. Mineralogical society, monograph 6, p480.
Oh, N. H. & Richter, D. D., 2005- Elemental translocation and loss from three highly weathered soil- bedrock profiles in the southeastern United States. Geoderma 126, 5-25.
Panahi, A.,Young, G. M. & Rainbird, R. H., 2000- Behavior of major and trace elements (including REE) during Paleoproterozoic pedogenesis and diagenetic alteration of an Archean granite near Ville Marie, Quebec, Canada. Geochimica et Cosmochimica Acta 64, 2199- 2220.
Rollinson, H., 1993- Using geochemical data: Evaluation, presentation, interpretation. Longman Scientific and Technical, 352p.
Schellmann, W., 1983- A new definition of laterite. Natural Resources and Development 18, 7-21.
Taylor, S. R. & McLennan, S. M., 1985- The continental crust: Its composition and evolution. Blackwell. Oxford, 312p.
Valeton, I., 1972- Bauxites. Elsevier, 226p.
White, A. F., Bullen, T. D., Schultz, M. S., Blum, A. E., Huntington, T. G.&Peters, N. E., 2001- Differential rates of feldspar weathering in granitic regoliths. Geochimica et Cosmochimica Acta 65, 847- 869.