Hydrology
Somayeh Esmaeili; Rahim Barzegar; Naeimeh Kazemian
Abstract
Qareh-Ziaeddin plain is located in the West Azarbaijan province, Northwest of Iran. The aim of this study is to investigate the effective factors and processes on the groundwater chemical quality of Qareh-Ziaeddin plain. For this purpose, 20 water samples were collected from groundwater resources in ...
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Qareh-Ziaeddin plain is located in the West Azarbaijan province, Northwest of Iran. The aim of this study is to investigate the effective factors and processes on the groundwater chemical quality of Qareh-Ziaeddin plain. For this purpose, 20 water samples were collected from groundwater resources in November 2016 and the concentration of the major ions, nitrate and silica was measured. Also, the pH and electrical conductivity of the samples were measured in the field. In this study, different bivariate and hydrochemical diagrams, chloro-alkaline index, saturation index and inverse modeling were used to achieve the mentioned goal. The results of the bivariate diagrams show that the saltwater intrusion from irrigation return flows, cation exchange, weathering and dissolution of rock minerals specially carbonates, silicates, gypsum and halite, and evaporation process, in a small amount, are the effective factors on the chemical quality of the groundwater in the study area. The calculated Chloro-alkaline indices indicate that these indices are negative in all samples, which reveal the normal ion exchange. The water samples are super-saturated with regards to the carbonate and quartz minerals, whereas are under-saturated with respect to the sulfate and halite minerals. The results of inverse geochemical modeling confirm weathering and dissolution of the carbonate, sulfate and halite minerals and ion exchange in different parts of the aquifer.
A Asghari Moghaddam; L Jalali
Abstract
The KhoyPlain is located in the north of West Azarbaijan province, northwest of Iran. The study area has a cold and arid climate with the annual mean precipitation of about 344 mm. The purpose of this study is evaluating of hydrochemical properties of groundwater and determination of arsenic contamination ...
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The KhoyPlain is located in the north of West Azarbaijan province, northwest of Iran. The study area has a cold and arid climate with the annual mean precipitation of about 344 mm. The purpose of this study is evaluating of hydrochemical properties of groundwater and determination of arsenic contamination at this plain. According to the hydrochemical analysis of 36 collected groundwater samples, in some zones of the area, arsenic contamination is exceed the world health organization (WHO) standard for drinking water. The arsenic concentrations of the water samples were increased in the east and southeast part of the study area. Based on the cluster analysis, the samples were posed in three clusters. Each of the clusters divided into subgroups based on heavy metals contain such as arsenic and iron. There is a positive correlation relationship between arsenic and iron, copper, sodium, chlorine, sulfate and EC. The high correlation of arsenic with iron and copper show the high impact of oxides and hydroxides of these elements in absorbing and accompanying in the sediments and consequently in the groundwater. The most saturation indices of arsenic were for FeAsO4:2H2O and Ca3 (AsO4)2:4H2O compounds, showing that change of saturation indices for these two compounds is similar and increasing from recharge to discharge area. Based on factor analysis method, three main effective factors were distinguished on hydrochemistry of the study area. In the first factor, chlorine, sodium, potassium, arsenic, copper, iron and electrical conductivity are effective elements, which have geogenic origin. Consequently, the origin of arsenic can be geogenicthatis related to geological factors, rocks and sediments that come from alteration of geological formations. Therefore, dissolution of minerals from the Miocene deposits such as marl, shale, sandstone and red conglomerate and the Pliocene conglomerate, and interbedded marl and sandstone are the effective sources of arsenic in the aquifer.
A. Asghari Moghaddam; E. Fijani
Abstract
Maku area is located in the north of West Azarbaijan, northwest of Iran. In this area, groundwater supplies main water demands for different purposes such as drinking, agriculture and industry. The aim of this research is to study the groundwater hydrochemistry, hydrogeological relation between karstic ...
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Maku area is located in the north of West Azarbaijan, northwest of Iran. In this area, groundwater supplies main water demands for different purposes such as drinking, agriculture and industry. The aim of this research is to study the groundwater hydrochemistry, hydrogeological relation between karstic and basaltic aquifers, determination of probable hydrochemical anomalies and their genesis and suitable methods for removal of these anomalies. For this purpose, in adition to available hydrochemical data, 72 water samples were collected from wells and springs in high and low level groundwater durations and were been analyzed for some trace elements. The results indicate fluoride anomaly in this area. In order to examine the hydrochemistry of the study area, graphical and mass balance methods were used. Both of these methods confirm the basaltic origin of fluoride anomalies. Consequently, hydrogeological relation between karstic and basaltic aquifer is established. Petrologic studies show that basaltic rocks of the area have appropriate conditions for occurrence of fluoroapatite; as a result, fluoroapatitic origin for high concentration of fluoride is identified. The most suitable methods for removal of the fluoride proposed to be adsorption on Defluoron2 and exchanging Cl- with F- by anionic resin in the study area.
