Document Type : Original Research Paper

Authors

1 M.Sc. Student , Research Institute for Earth Sciences, Geological Survey of Iran, Tehran, Iran

2 Associate Professor, Research Institute for Earth Sciences, Geological Survey of Iran,Tehran, Iran

3 Associate Professor, Department of Geology, Faculty of Sciences, University of Zanjan, Iran

Abstract

Cenozoic acidic volcanic rocks at the south of Qezel Ozan River are located within the Western Alborz-Azarbaijan magmatic zone and northern part of the Iranian-Turkish Plateau. The Oligocene acidic lavas in north part of Zanjan show rhyolitic to dacitic composition.  Hyaloporphyritic to hyalomicrolithic porphyritic textures are the main texture in these rocks. They were erupted along the main faults in this area. Feldspars, biotites and hornblendes are the major phenocrysts which are embedded in a glass matrix or micro phenocrysts of felsic and mafic minerals. By Geochemical studies it is indicated that these rocks have high-K calc-alkaline to shoshonitic nature and classified as meta-aluminous and I-type acidic rocks. In the chondrite normalized rare earth elements diagram, these rocks demonstrate LREE enrichment and high LREE/HREE ratio. Enrichment in LREE and depletion in HREE is characteristic of the calc-alkaline rocks in active continental margins. Furthermore, these rocks show enrichment in LILEs and negative anomalies of HFSEs (Ti, Nb and Ta) which is the feature of magmatic rocks associated with Post-COLG subduction zones. The geochemical evidences suggest that the parental acidic magma is resulted from partial melting of lower crust as a result of pressure reduction during the local tension mechanism.

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Bucher, K. and Frey, M., 1994- Petrogenesis of Metamorphic Rocks. Berlin: Springer. https://doi.org/10.1007/978-3-662-04914-3. 
Chappell, B. W. and White, A. J. R., 1974- Two Contrasting Granite Types, Pac. Geology 8: 173-174.  https://doi.org/10.1046/j.1440-0952.2001.00882.x.
Chen, W. and Arculus, R. J., 1995- Geochemical and isotopic characteristics of lower crustal xenoliths, San  Francisco Volcanic Field, Arizona, U.S.A. Lithos 110, p. 99–119. https://doi.org/10.1016/0024-4937(95)00018-6 
Cheng, H. C., Shan, H. C., Hue, H. H., Chang, H, C. and Sun, L. C., 2001- Petrology and geochemistry of Neogene continental basalts and related rocks in northern Taiwan (III): Alkali Basalts and Tholeiites from Shiting-Yinko Area. Western Pacific earth scinces. Vol.1, No., 1. pp:19-46 http://old.gst.org.tw/WPES/database/WPES_V1_N1_P19.pdf.
Clark, G. C., Davies, R. G., Hamzepour, G. and Jones, R. C., 1975- Explanatory text of the Banddar-e-Pahlavi quadrangle map 1:250 000, Geological Survey of Iran, Tehran. http://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=PASCALGEODEBRGM8220055715.  
Edwards, C., Menzies, M. and Thirlwall, M., 1991- Evidence from Muriah, Indonesia, for the interplay of supra-subduction zone and intraplate processes in the genesis of potassic alkaline magmas. Journal of  Petrology 32: 555-592. https://doi.org/10.1093/petrology/32.3.555 .
 Fitton, J. G., James, D. and Leeman, W. P., 1991- Basic magmatism associated with Late Cenozoic extension in the western United States: Compositional variations in space and time, Journal of geophysical Research: Solid earth 96 (B8), 13693-13711, https://doi.org/10.1029/91JB00372. 
Gill, J. B., 1981- Orogenic andesites and plate tectonics: New York, Springer Verlag, 390 p. https://doi.org/10.1007/978-3-642-68012-0 .
Green, N. L., 2006- Influence of slab thermal structure on basalt source regions and melting conditions: REE and HFSE constraints from the Garibaldi volcanic belt, northern Cascadia subduction system. Lithos 87: 23-49. https://doi.org/10.1016/j.lithos.2005.05.003 .
Harker, A., 1909- The natural history of igneous rocks. Methuen, London.344p. https://doi.org/10.1017/CBO9780511920424.
Hastie, A. R., Kerr, A. C., Pearce, J. A. and Mitchell, S. F., 2007- Classification of altered volcanic arc rocks using immobile trace elements: development of the Th- Co discrimination diagram. Journal of Petrology 48(12): 2341- 2357. https://doi.org/10.1093/petrology/egm062.
Henderson, P., 1984- Rare Earth Element Geochemistry. Elsevier, Oxford, New York, US 2: 1-510. https://www.sciencedirect.com/bookseries/developments-in-geochemistry/vol/2/suppl/C.
Irvine, T. N. J. and Baragar, W. R. A. F., 1971- A guide to the chemical classification of the common volcanic rocks. Canadian Journal of Earth Sciences 8: 523-548. https://doi.org/10.1139/e71-055 .
Jackson, J., Priestley, K., Allen, M. and Berberian, M., 2002- Active tectonics of the south Caspian Basin. Geophysical Journal International, 148, 214-245. https://doi.org/10.1046/j.1365-246X.2002.01588.x .
Keskin, M., Pearce, J. A. and Mitchell, J. G., 1998- Volcano-stratigraphy and geochemistry of collision-related volcanism on the Erzurum-Kars Plateau, northeastern Turkey. Journal of Volcanology and Geothermal Research 85,355-404. https://doi.org/10.1016/S0377-0273(98)00063-8.
Kheirkhah, M., Allen, M.B., Emami, M., 2009- Quaternary syn-collision magmatism from the Iran/Turkey borderlands. Journal of Volcanology and Geothermal Research, 182, 1-2,. http://dx.doi.org/10.1016/j.jvolgeores.2009.01.026.
Le Bas, M. J., Le Maitre, R. W., Streckeisen, A. and Zanettin, B., 1986- A chemical classification of volcanic rocks based on the total alkali-silica diagram. Journal of Petrology 27: 745-750. https://doi.org/10.1093/petrology/27.3.745.
Lescuyer, J. I., Riou, R., 1976- Géologie de la région de Mianeh (Azarbaijan). Contribution de la volcanisme tertiare de l’ Iran. Thèse 3 cycle, Grenoble, 234 p. https://tel.archives-ouvertes.fr/tel-00759449.
Lofgren, G, E., 1971- Spherulitic textures in glassy and crystalline rock. Journal of Geophysical Research, 76, 5635-48. https://doi.org/10.1029/JB076i023p05635 .
Mason, B. J. and Moor, C. B., 1982- Principle of geochemistry, New York, pp. 344. https://www.resolutionmineeis.us/documents/mason-moore-1982.
McDonough, W. F. and Sun, S. S., 1995- Composition of the Earth. Chemical Geology 120: 223–253. https://doi.org/10.1016/0009-2541(94)00140-4 .
McPhie, J., Doyle, M. and Allen, R., 1993- Volcanic textures: a guide to the interpretation of textures in volcanic rocks, Uni. Tasmania, 198pp. http://www.worldcat.org/oclc/30616232.  
Menuge, J. F., Brewer, T. S. and Seeger, C. M., 2002- Petrogenesis of metaluminous A-type rhyolites from the St Francois Mountains, Missouri and the Mesoproterozoic evolution of the southern Laurentian margin. Precambrian Research 113(3-4): 269-291. https://doi.org/10.1016/S0301-9268(01)00211-X.
Orozco-Esquivel, T., Pwtrone, C. M., Ferrari, L., Tagami, T. and Manetti, P., 2006- Geochemical variabilityin lavas from the eastern Trans-Mexican volcanic belt: slab detachment in a subduction zone with varying dip. Lithos 93:149-174. https://doi.org/10.1016/j.lithos.2006.06.006. 
Patino Douce, A. E., 1996- Effects of pressure and H2O content on the compositions of primaty crustal melts, Trans R Soc Edinburgh Earth Sci 87.11-21. https://doi.org/10.1017/S026359330000643X .
Pearce, J. A., Harris, N. B. W. and Tindle, A. G., 1984- Trace element discrimination diagrams for the tectonic interpretation of granitic rocks. Journal of Petrology 25: 956- 983.  https://doi.org/10.1093/petrology/25.4.956.
Rollinson, H., 1993- Using geochemical data: evaluation, presentation, interpretation langmon. https://doi.org/10.4324/9781315845548.
Salvi, S. and Williams-Jones, A. E., 1996- The role of hydrothermal processes in concentrating high field strength elements in the Strange Lake peralkaline complex, northeastern Canada., Geochimica et Cosmochimica Acta 60: 1917-1932. https://doi.org/10.1016/0016-7037(96)00071-3 .
Shand, S. J., 1943- The eruptive rocks. 2nd edition, John Wiley, New York, US. 444pp. 
Smith, E. I, Sánchez, A., Walker, J. D. and Wang, K., 1999- Geochemistry of mafic magmas in the Hurricane Volcanic field, Utah: implications for small- and large-scale chemical variability of the lithospheric mantle, J Geol 107, p. 433-448. https://doi.org/10.1086/314355.
Stocklin, J., 1968- Structural history and tectonics of Iran: A review. The American Association of Petroleum Geologists Bulletin, k. 52, No.7, 1229-1258, 10 fig. https://doi.org/10.1306/5D25C4A5-16C1-11D7-8645000102C1865D. 
Taylor, S. R.  and  McLennan, S. M., 1981- The Composition and Evolution of the Continental Crust: Rare Earth Element Evidence from Sedimentary Rocks. Developments in Precambrian Geology, Volume 4, 1981, Pages 527-548, https://doi.org/10.1016/S0166-2635(08)70026-4.
Thompson, A. B., 1982- Dehydration melting of crustal rocks and the generation of H2O under saturated granitic liquids. American Journal of Science, 282: 10-1567. https://doi.org/10.2475/ajs.282.10.1567. 
Verdel, C., B. P. Wernicke, J. Hassanzadeh, and B. Guest., 2011- A Paleogene extensional arc flare – up in Iran, Tectonics, 30, TC3008. https://doi.org/10.1029/2010TC002809.
Weaver, B. and Tarney, J., 1984- Empirical approach to estimating the composition of the continental crust.Nature, 310: 575-57. https://doi.org/10.1038/310575a.
Zanetti, A., Mazzucchelli, M., Rivalenti, G. and Vannuci, R., 1999- The Finero phlogopite- peridotite massif: an example of subduction- related metasomatism. Contributions to Mineralogy and Petrology 134: 107- 122. https://doi.org/10.1007/s004100050472.