Document Type : Original Research Paper

Authors

1 Assistant Professor, Department of Earth Sciences, Faculty of Sciences, University of Kurdistan, Sanandaj, Iran

2 Professor, Department of Mining Engineering, Faculty of Engineering, University of Kurdistan, Sanandaj, Iran

3 M.Sc., Department of Earth Sciences, Faculty of Sciences, University of Kurdistan, Sanandaj, Iran

Abstract

The Upper Cretaceous succession (UCS) of the north Sanandaj-Sirjan zone consists of five units. The units are 2000 m thick, including shale, sandstone, limestone, intrafomational conglomerate with interbedded basaltic- andesitic lava. This succession is unconformably underlain by Lower Cretaceous and overlain by Paleocene conglomerates. The geochemistry of the samples represents ratios of Al2O3/TiO2 (18-22), La/LuCN (5.43-24.4), La/Sc (0.51-2.53), Th/Sc (0.42-0.68), LREE/HREE (Nd/ErCN > 5), and negative anomalies of Eu/Eu* (0.26-0.89) and Nb/Nb* (0.14-0.82). These characteristics indicate that the samples are immature, first-order sediments, and were eroded from intermediate to acidic arcs in the subduction zone. The volcanic rocks were formed during the intracrustal melting of an altered oceanic slab at high pressures in the garnet-amphibolite facies. The geochemical compositions and vertical lithofacies stacking patterns of the UCS imply that the depositional environment has changed during sedimentation from a trench to trench slope and forearc basins arising from continent-ward migration of the magmatic arc. The activities of Late Cretaceous volcanism resulted in the upwelling of anoxic water, demise of planktonic, and formed pyrite in the deposits. Samples on the Th/Yb-Ta/Yb diagram fall in the ACM and WPVZ fields, indicating tectonic evolution from low-gradient subduction to extensional volcanic conditions.

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References
Agard, P., Omrani, J., Jolivet, L., Whitchurch, H., Vrielynck, B., Spakman, W., Monié, P., Meyer, M. and Wortel, R., 2011- Zagros orogeny: A subduction-dominated process. Geological Magazine, 148(5-6): 692-725. https://doi.org/10.1017/S001675681100046X.
Alavi, M., 1994- Tectonics of the Zagros orogenic belt of Iran: new data and interpretations. Tectonophysics, 229
(3-4): 211-238. https://doi.org/10.1016/0040-1951(94)90030-2.
Alavi, M., 2007- Structures of the Zagros fold thrust belt in Iran. American Journal of Science, 307(9): 1064-1095. https://doi.org/10.2475/09.2007.02.
Arthur, M. A., Schlanger, S. O. and Jenkyns, H.C., 1987- The Cenomanian- Turonian Oceanic Anoxic Event, II. Palaeoceanographic controls on organic-matter production and preservation. In: J. Brooks and A.J. Fleet (eds.), Marine Petroleum Source Rocks. Geological Society, London, Special Publ., 26: 401-420. ISBN 13: 9780632011377.
Azizi, H. and Jahangiri, A., 2008- Cretaceous subduction-related volcanism in the northern Sanandaj-Sirjan Zone, Iran. Journal of Geodynamics, 45(4-5): 178-190. https://doi.org/10.1016/j.jog.2007.11.001.
Azizi, H. and Moinevaziri, H., 2009- Review of the tectonic setting of Cretaceous to Quaternary volcanism in northwestern Iran. Journal of Geodynamics, 47(4): 167-179. https://doi.org/10.1016/j.jog.2008.12.002.
Baier, J., Audétat, A. and Keppler, H., 2008- The origin of the negative niobium tantalum anomaly in subduction zone magmas. Earth and Planetary Science Letters, 267(1-2): 290-300. https://doi.org/10.1016/j.epsl.2007.11.032
Bailleul, J., Robin, C., Chanier, F., Guillocheau, F., Field, B.D. and Ferrière, J., 2007- Turbidite systems in the inner forearc domain of the Hikurangi convergent margin (New Zealand): new constraints on the development of trench-slope basins. Journal of Sedimentary Research, 77(4): 263-283. https://doi.org/10.2110/jsr.2007.028.
Bau, M., 1996- Controls on the fractionation of isovalent trace elements in magmatic and aqueous systems: evidence from Y/Ho, Zr/Hf and lanthanide tetrad effect. Contributions to Mineralogy and Petrology, 123: 323-333. https://doi.org/ 10.1007/s004100050159.
Berberian, F. and Berberian, M., 1981- Tectono-plutonic episodes in Iran. American Geophys Union Geodynamic Series, 3: 5-32. https://doi.org/10.1029/GD003p0005.
Berberian, M. and King, G. C. P., 1981- Towards a paleogeography and tectonic evolution of Iran. Canadian Journal of Earth Sciences, 18(2): 210-265. https://doi.org/10.1139/e81-019.
Bhatia, M. R., 1983- Plate tectonics and geochemical composition of sandstones. Journal of Geology, 91(6): 611-627. https://doi.org/10.1086/628815
Bhatia, M. R. and Crook, K. A. W., 1986- Trace element characteristics of graywackes and tectonic setting discrimination of sedimentary basins. Contributions to Mineralogy and Petrology, 92: 181-193. http://dx.doi.org/10.1007/BF00375292.
Bock, B., McLennan, S. M. and Hanson, G. N., 1998- Geochemistry and provenance of the Middle Ordovician Austin Glen Member (Normanskill Formation) and the Taconian Orogeny in New England. Sedimentology, 45(4): 635-655. https://doi.org/10.1046/j.1365-3091.1998.00168.x.
Brumsack, H. J., 2006- The trace metal content of recent organic carbon-rich sediments: Implications for Cretaceous black shale formation. Palaeogeography, Palaeoclimatology, Palaeoecology, 232(2-4): 344-361. https://doi.org/10.1016/j.palaeo.2005.05.011.
Cerny, P., Meintzer, R. E. and Andreson, A. J., 1985- Extreme fractionation in rare-element granitic pegmatites: selected examples of data and mechanisms. Canadian Mineralogist, 23(3): 381-421.
Cherven, V. B., 1986- Tethys-marginal sedimentary basins in western Iran. GSA Bull., 97(5): 516-522. https://doi.org/10.1130/0016-7606(1986)97<516:TSBIWI>2.0.CO;2.
Condie, K.C. and Wronkiewicz, D. J., 1990- A new look at the Archean-Proterozoic boundary: sediments and tectonic setting constraint. Developments in Precambrian Geology, 8: 61-83pp. https://doi.org/10.1016/S0166-2635(08)70162-2.
Correia Neves, J. M., Lopes Nunes, J. E. and Sahama, T. G., 1974- High hafnium members of the zircon-hafnon series from the granite pegmatites of Zambézia, Mozambique. Contributions to Mineralogy and Petrology, 48: 73-80. https://doi.org/10.1007/BF00399111.
Cox, R., Lowe, D. R. and Cullers, R. L., 1995- The influence of sediment recycling and basement composition on evolution of mudrock chemistry in the southwestern United States. Geochimica et Cosmochimica Acta, 59(14): 2919-2940. https://doi.org/10.1016/0016-7037(95)00185-9.
Cullers, R. L., 2000- The geochemistry of shales, siltstones and sandstones of Pennsylvanian-Permian age, Colorado, USA: implications for provenance and metamorphic studies. Lithos, 51(3): 181-203. https://doi.org/10.1016/S0024-4937(99)00063-8.
Dill, H., Teshner, M. and Wehner, H., 1988- Petrography, inorganic and organic geochemistry of Lower Permian Carboniferous fan sequences (Brandschiefer Series) FRG: constraints to their palaeogeography and assessment of their source rock potential. Chemical Geology, 67(3-4): 307-325. https://doi.org/10.1016/0009-2541(88)90136-2
Dostal, J., Keppie, B. L., Cousens, J.B. and Murphy, J.B., 1996- 550-580 Ma magmatism in Cape Breton Island (Nova Scotia, Canada): the product of NW-dipping subduction during the final stage of amalgamation of Gondwana. Precambrian Research, 76(1-2): 93–113. https://doi.org/10.1016/0301-9268(96)00040-X.
Dostal, J. and Chatterjee, A.K., 2000- Contrasting behavior of Nb/Ta and Zr/Hf ratios in a peraluminous granitic pluton (Nova Scotia, Canada). Chemical Geology, 163(1-4): 207-218. https://doi.org/10.1016/S0009-2541(99)00113-8.
Draut, A. E. and Clift, P.D., 2012- Basins in arc-continent collisions. In: C. Busby and A. Azor (eds.), Tectonics of Sedimentary Basins: Recent Advances. Blackwell, 347-368 pp. https://doi.org/10.1002/9781444347166.ch17.
Eby, G. N., 1992- Chemical subdivision of the A-type granitoids: petrogenetic and tectonic implications. Geology, 20(7): 641-644. https://doi.org/10.1130/0091-7613.
Erturk, M.A., Beyarslan, M., Chung, S. L. and Lin, T. H., 2018-  Eocene magmatism (Maden Complex) in the Southeast Anatolian Orogenic Belt: Magma genesis and tectonic implications. Geoscience Frontiers, 9(6): 1829-1847. https://doi.org/10.1016/j.gsf.2017.09.008.
Fedo, C. M., Nesbitt, H. W. and Young, G. M., 1995- Unraveling the effects of potassium metasomatism in sedimentary rocks and paleosols, with implications for paleoweathering conditions and provenance. Geology, 23(10): 921-924. https://doi.org/10.1130/0091-7613(1995)023<0921:UTEOPM>2.3.CO;2.
Feng, R. and Kerrich, R., 1990- Geochemistry of fine-grained clastic sediments in the Archean Abitibi greenstone belt, Canada: Implications for provenance and tectonic setting. Geochimica et Cosmochimica Acta, 54(4): 1061-1081. https://doi.org/10.1016/0016-7037(90)90439-R.
Floyd, P.A., Kelling, G., Gökçen, S. L. and Gökçen, N., 1991- Geochemistry and tectonic environment of basaltic rocks from the Misis Ophiolitic Melange, south Turkey. Chemical Geology, 89: 263-280. https://doi.org/10.1016/0009-2541(91) 90020-R.
Garver, J. I. and Scott, T. J., 1995- Trace elements in shale as indicators of crustal provenance and terrane accretion in the southern Canadian Cordillera GSA Bull, 107(4): 440-453. https://doi.org/10.1130/0016-7606(1995)107<0440: TEISAI>2.3.CO;2
Green, T. H., 1995- Significance of Nb/Ta as an indicator of geochemical processes in the crust mantle system, Chemical Geology, 120(3-4): 347-359. https://doi.org/10.1016/0009-2541(94)00145-X.
Guo, Q., Xiao, W., Windley, B.F., Mao, Q., Han, C., Qu, J., Ao, S., Li, J., Song, D. and Yong, Y., 2012- Provenance and tectonic settings of Permian turbidities from the Beishan Mountains, NW China: Implications for the Late Paleozoic accretionary tectonics of the southern Altaids. Journal of Asian Earth Sciences, 49: 54-68. https://doi.org/10.1016/j.jseaes.2011.03.013.
Harnois, L., 1988- The CIW index: A new chemical index of weathering. Sedimentary Geology, 55(3-4): 319-322. https://doi.org/10.1016/0037-0738(88)90137-6.
Hatch, J. R. and Leventhal, J. S., 1992- Relationship between inferred redox potential of the depositional environment and geochemistry of the Upper Pennsylvanian (Missourian) Stark Shale Member of the Dennis Limestone, Wabaunsee County, Kansas, U.S.A. Chemical Geology, 99(1-3): 65-82. https://doi.org/10.1016/0009-2541(92)90031-Y.
Hayashi, K., Fujisawa, H., Holland, H. D. and Ohmoto, H., 1997- Geochemistry of 1.9 Ga sedimentary rocks from northeastern Labrador, Canada. Geoch. et Cosm. Acta, 61(19): 4115-4137. https://doi.org/10.1016/S0016-7037(97)00214-7.
Herron, M. M., 1988- Geochemical classification of terrigenous sands and shales from core or log data. Journal of Sedimentary Research, 58(5): 820-829. https://doi.org/10.1306/212F8E77-2B24-11D7-8648000102C1865D.
Jenkyns, H. C., 1980- Cretaceous anoxic events: From continents to oceans. Geological Society, London, Special Publication, 137: 171-188. https://doi.org/10.1144/gsjgs.137.2.0171.
Kremer, I. and Tishin, P. A., 2017- Composition and conditions of the late Mesozoic volcanism occurrence of the northern part of the Borschovochny ridge (Eastern Transbaikalia). IOP Conf. Series: Earth and Environmental Science, 110. https://doi.org/10.1088/1755-1315/110/1/012011.
LeBas, M. J., Le Maitre, R. W., Streckeisen, A. and Zanettin, B., 1986- A chemical classification of volcanic rocks based on the total alkali silica diagram. Journal of Petrology, 27(3): 745–750. https://doi.org/10.1093/ petrology/27.3.745
Linnen, L.R. and Keppler, H., 2002- Melt composition control of Zr/Hf fractionation in magmatic processes. Geochimica et Cosmochimica Acta, 66(18): 3293-3301. https://doi.org/10.1016/S0016-7037(02)00924-9
McLennan, S. M., 1989 -Rare Earth Elements in Sedimentary Rocks; Influence of Provenance and Sedimentary Processes. Reviews in Mineralogy and Geochemistry, 21(1): 169-200. http://rimg.geoscienceworld.org/content/21/1/ 169.s.
McLennan, S.M., 2001- Relationship between the trace element composition of sedimentary rocks and upper continental crust. Geochemistry, Geophysics, Geosystems, 2 (4): 1-24. https://doi.org/10.1029/2000GC000109.
McLennan, S. M., Taylor, S.R., and Eriksson, K.A., 1983- Geochemistry of Archean shales from the Pilbara Supergroup, Western Australia. Geoch. et Cosmoch. Acta, 47: 1211-1222. https://doi.org/10.1016/0016-7037(83) 90063-7.
McLennan, S. M. and Taylor, S.R., 1991- Sedimentary Rocks and Crustal Evolution: Tectonic Setting and Secular Trends. Journal of Geology, 99(1): 1-21. http://dx.doi.org/10.1086/629470.
McLennan, S.M., Hemming, S., McDaniel, D.K. and Hanson, G. N., 1993- Geochemical approaches to sedimentation, provenance and tectonics. GSA, Special Paper, 285: 21-40. https://doi.org/10.1130/SPE284-p21.
Mohajjel, M. and Fergusson, C. L., 2000- Dextral transpression in Late Cretaceous continental collision, Sanandaj–Sirjan Zone, western Iran. Journal of Structural Geology, 22(8): 1125-1139. https://doi.org/10.1016/S0191-8141(00)00023-7.
Molinaro, M., Zeyen, H. and Laurencin, X., 2005- Lithospheric structure beneath the southeastern Zagros Mountains, Iran: recent slab break-off? Terra Nova, 17(1): 1-6. https://doi.org/10.1111/j.1365-3121.2004.00575.x.
Morata, D., Aguirre, L., Féraud, G. and Belmar, M., 2005- Geodynamic implications of the regional very low-grade metamorphism in the Lower Cretaceous of the Coastal Range in Central Chile. 6th International Symposium on Andean Geodynamics Barcelona, 531-534.
Nesbitt, H. W. and Young, Y. M., 1982- Early Proterozoic climates and plate motions inferred from major element chemistry of lutites. Nature, 299(5885): 715-717. https://doi.org/10.1038/299715a0.
Nwaila, G., Frimmel, H. E. and Minter, W. E. L., 2017- Provenance and geochemical variations in shales of the Mesoarchaean Witwatersrand Supergroup. Journal Geology, 125(4): 399-422. https://doi.org/10.1086/692329.
Parker, A., 1970- An index of weathering for silicate rocks. Geological Magazine, 107(6): 501-504. https://doi.org/10.1017/ S0016756800058581.
Pearce, J. A., 1983- Role of the subcontinental lithosphere in magma genesis at active continental margins. In: C.J. Hawkesworth and M.J. Norry (eds.), Continental Basalts and Mantle Xenoliths. Nantwich, UK: Shiva Press, 230-249. ISBN: 0906812348.
Peccerillo, A. and Taylor, S.R., 1976- Geochemistry of Eocene calc-alkaline volcanic rocks from the Kastamonu area, northern Turkey. Contributions to Mineralogy and Petrology, 58: 63-81. https://doi.org/10.1007/BF00384745.
Pi, D.H., Liu, C.-Q., Shields-Zhou, G.A. and Jiang, S.-Y., 2013- Trace and rare earth element geochemistry of black shale and kerogen in the early Cambrian Niutitang Formation in Guizhou Province, South China: constraints for redox environments and origin of metal enrichments. Precambrian Reserch, 225: 218-229. https://doi.org/10.1016/j.precamres.2011.07.004.
Price, J. R. and Velbel, A. M., 2003- Chemical weathering indices applied to weathering profiles developed on heterogeneous felsic metamorphic parent rocks. Chemical Geology, 202(3-4): 397-416. https://doi.org/10.1016/j. chemgeo.2002.11.001.
Rogers, J. J. W. and Adams, J.A.S., 1969- Uranium and Thorium. In: K.H. Wedepohl (ed.), Handbook of Geochemistry. Springer, Berlin, 11-14pp. ISBN: 978-3-642-46302-0.
Roser, B.P. and Korsch, R. J., 1986- Determination of tectonic setting of sandstone–mudstone suites using SiO2 content and K2O/Na2O ratio. Journal of Geology, 94(5): 635-650. https://doi.org/10.1086/629071.
Roy, D. K. and Roser, B.P., 2013- Climatic control on the composition of Carboniferous–Permian Gondwana sediments, Khalaspir basin, Bangladesh. Gondwana Research, 23(3): 1163-1171. https://doi.org/10.1016/j.gr. 2012.07.006.
Rudnick, R.L., Barth, M., Horn I., and McDonough, W.F., 2000- Rutile-bearing refractory eclogites: missing link between continents and depleted mantle. Science, 287(5451): 278-281. https://doi.org/10.1126/science.287.5451.278.
Schlanger, S.O., Arthur, M.A., Jenkyns, H.C., and Scholle, P.A., 1987- The Cenomanian-Turonian Oceanic Anoxic Event, I. Stratigraphy and distribution of organic carbon-rich beds and the marine δ13C excursion. In: J. Brooks and A.J. Fleet (eds.), Marine Petroleum Source Rocks. Geological Society, London, Special Publication, 26: 371-399. https://doi.org/10.1144GSL.SP.1987.026.01.24.
Sambasiva Rao, V.V., Sreenivas, B., Balaram, V., Govil, P.K., and Srinivasan, R., 1999- The nature of the Archean upper crust as revealed by the geochemistry of the Proterozoic shales of the Kaladgi basin, Karnataka, southern India. Precambrian Research, 98(1-2): 53-65. https://doi.org/10.1016/S0301-9268(99)00038-8.
Stöcklin, J., 1968- Structural history and tectonics of Iran, a review. AAPG Bulletin, 52(7): 229-1258. https://doi.org/10.1306/5D25C4A5-16C1-11D7-8645000102C1865D.
Sullivan, R.W. and van Staal, C.R., 1996- Preliminary chronostratigraphy of the Tetagouche and Fournier groups in northern New Brunswick; hi Radiogenic Age and Isotopic Studies. Geological Survey of Canada, Report 9; Current Research I995-F, 43-56 pp.
Suttner, L.J., and Dutta, P.K., 1986- Alluvial sandstone composition and paleoclimate. Framework mineralogy. Journal of Sedimentary Petrology, 56(3): 326–345. https://doi.org/10.1306/212F8909-2B24-11D7-8648000102C1865D.
Taylor, S. R., 1977- Island arc models and the composition of the continental crust. In: M. Talwani and W.C. Pitman (eds.), Island arcs, deep-sea trenches, and back arc basins. American Geophysical Union Maurice Ewing Series, 1: 325-335. https://doi.org/10.1029/ME001p0325
Taylor, S.R. and McLennan, S. M., 1995- The geochemical evolution of the continental crust. Reviews of Geophysics, 33 (2): 241-265. https://doi.org/10.1029/95RG00262.
Uchman, A., Abbassi, N. and Naeeji, M.R., 2005- Persichnusigen. nov., and associated ichnofossils from the upper Cretaceous to Eocene deep-sea deposits of the Sanandaj area, West Iran. Ichnos, 12(2): 141-149. https://doi.org/10.1080/10420940590914624.
Wang, L., Huang, C.C., Pang, J., Zha, X. and Zhou, Y., 2014- Paleofloods recorded by slack-water deposits in the upper reaches of the Hanjiang River valley, middle Yangtze River basin, China. Journal Hydrology, 519: 1249-1256. https://doi.org/10.1016/j.jhydrol.2014.08.002.
Wang, Z., Yan, Z., Ma, Z., He, S., Fu, C. and Wang, D., 2016- Geochronological and Geochemical evidence of amphibolite from the Hualong Group, northwest China: Implication for the early Paleozoic accretionary tectonics of the Central Qilian belt. Lithos, 248-251: 12-21. https://doi.org/10.1016/j.lithos.2016.01.012
Winchester, J. A. and Floyd, P. A., 1977- Geochemical discrimination of different magma series and their differentiation products using immobile elements. Chemical Geology, 20: 325-343. https://doi.org/10.1016/0009-2541(77)90057-2.
Yamamoto, K., Sugisaki, R. and Arai, F., 1986- Chemical aspects of alteration of acidic tufts and their application to siliceous deposits. Chemical Geology, 55(1-2): 61-76. https://doi.org/10.1016/0009-2541(86)90128-2.
Zahedi, M. and Hajian, J., 1985- Geology map of Sanandaj. Scale 1:250000. No. C5, Geology Survey of Iran.