Economic Geology
Robabe masoomi; Yoseph Rahimsouri; Hemayat Jamali; Ali Abedini
Abstract
The action of alteration processes on the Eocene tuffs has led to the formation of a spread argillic alteration zone in the Kamar district (south of Ardebil, Tarom-Hashtjin Zone). The aim of this study is to determine the factors controlling argillic alteration, using mineralogical studies and chemical ...
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The action of alteration processes on the Eocene tuffs has led to the formation of a spread argillic alteration zone in the Kamar district (south of Ardebil, Tarom-Hashtjin Zone). The aim of this study is to determine the factors controlling argillic alteration, using mineralogical studies and chemical alteration indices. Quartz, kaolinite, muscovite (sericite), rutile, anatase, illite, diaspore, alunite, albite, clinochlore, jarosite, gypsum, pyrite, orthoclase and dolomite are the mineral assemblage of this alteration zone. The mineralization of sulfides includes pyrite (predominantly), chalcopyrite, borneite, chalcocite, galena, and sphalerite. The chemical index of alteration (CIA) values are between 51.55 to 74.3 %, and the mineralogical index of alteration (MI) values vary from 8.22 to 48.3%. The mafic index of alteration (MIA(O)) ranges from 55.88% to 87.48%, Depletion of a large number of elements, including some immobile elements (Zr, Y, V, Al and LREEs), the presence of minerals indicating acidic pH, such as jarosite and alunite, and high-temperature minerals such as rutile and anatase, the presence of the vuggy quartz in some altered regions, and concomitant enrichment of As, Sb and Mo, in the Kamar argillic zone, bear similarities to the hot fluid alterations of high-sulfidation epithermal deposits.
B. Sameti; A. Zia Zarif; M. R. Jafari; A. Darvishzadeh
Abstract
The study area is located in Farash 1:50000 sheet in Kerman province, at a distance of about 50 kilometers from the Jiroft-Darb Behesht road in the Jebalbarez zone. The study area is located in Bam 1:250000 sheet in the Sanandaj-Sirjan structural zone. Rock units include granite, granodiorite and volcano-sedimentary ...
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The study area is located in Farash 1:50000 sheet in Kerman province, at a distance of about 50 kilometers from the Jiroft-Darb Behesht road in the Jebalbarez zone. The study area is located in Bam 1:250000 sheet in the Sanandaj-Sirjan structural zone. Rock units include granite, granodiorite and volcano-sedimentary rocks combined with tuff, nummulite limestone, conglomerate and agglomerate. Due to intrusion of igneous rocks in the southern part of limestone and tuff, iron skarn mineralization is occurred. Using processing and interpretation of 1030 data ground magnetic survey with lines space of 25 meters and preparing maps of magnetic intensity and using data layers such as geological and tectonic maps, areas with potential mineralization of iron ore were introduced. After field control, it was cleared that the main outcrops of iron ore are concentrated in the central parts of the South East. The main host iron ore are skarn and granite in the middle part of the area. Trend of mineralization is NW-SE and main minerals of iron are magnetite and hematite. Iron mineralization are also occurred in zones of argillic and propylitic alteration.
Behnaz Barghi; Ali Asghar Calagari; Mohammad Hossein Zarrinkoub; Vartan Simmonds
Abstract
Mn-bearing veins of Jonub -ESehchangi are located 200 km southwest of Birjand, Southern Khorasan province (east of Iran). These veins are hosted by andesitic rocks of Eocene to Oligocene ages. Ore minerals identified by XRD method and mineralographic studies and are Pyrolusite, cryptomelane, psilomelane, ...
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Mn-bearing veins of Jonub -ESehchangi are located 200 km southwest of Birjand, Southern Khorasan province (east of Iran). These veins are hosted by andesitic rocks of Eocene to Oligocene ages. Ore minerals identified by XRD method and mineralographic studies and are Pyrolusite, cryptomelane, psilomelane, hollandite, hematite and goethite, displaying colloform and open-space filling textures. Gypsum, halite, barite, carbonate and silica are the gangue minerals. Alteration zones, specifically argillic alteration zone, are developed along the vein within the andesitic wall rocks. Based on the mineralogical and geochemical data, the primary manganese minerals were Mn oxides and hydroxides, which have gradually been converted to psilomelane and hollandite, and finally pyrolusite. The average grade of Mn within the veins is 38.61%. Considering the average Mn/Fe ratio (about 48.55) in the Mn-bearing veins, as well as the positive correlation of Sr, U and Ba with Mn mineralization in this area show hydrothermal origin.
A. Abedini
Abstract
Intrusion of quartz-monzodioritic igneous bodies of Oligocene age into the Eocene lithic crystal tuffs and trachy-basalts resulted in occurrence of widespread argillic alteration zone in the Jizvan area (Tarom-Hashtjin zone). Mineralogical studies indicate that this alteration zone includes kaolinite, ...
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Intrusion of quartz-monzodioritic igneous bodies of Oligocene age into the Eocene lithic crystal tuffs and trachy-basalts resulted in occurrence of widespread argillic alteration zone in the Jizvan area (Tarom-Hashtjin zone). Mineralogical studies indicate that this alteration zone includes kaolinite, quartz, smectite, pyrophyllite, muscovite-illite, alunite, rutile, calcite, feldspar, chlorite, hematite and goethite minerals. Hypogene ore minerals within the silicic-carbonatic veins and veinlets of argillic alteration zone contain chalcopyrite, galena and pyrite accompanied by goethite, malachite and azurite of supergene origin. Mass changes calculations of elements with assumption of Al as a monitor immobile element indicate that elements such as Ti, P, Th, Nb, Ta, Y and Zr have suffered leaching during argillization of lithic crystal tuffs. This abnormal behaviour is in relation to low pH of altering solutions, high water/rock ratio, abundance of complexing ions and suitable drainage system. The distribution pattern of REEs normalized to chondrite shows differentiation and enrichment of LREEs relative to HREEs and occurrence of negative Eu and Ce anomalies during argillization of lithic crystal tuffs. Geochemical investigations reveal that occurrence of negative Ce anomaly (0.49-0.92) is in relation to the destruction of zircon by acidic-oxidizing fluids. Negative Eu anomaly (0.23-0.73) and mass loss of elements such as Si, Fe, K, Rb, Cs, Sr and Ba indicate destruction of plagioclase and hornblende by strongly acidic hydrothermal fluids and high oxygen fugacity of environment. The correlation coefficients between elements display the controlling role of Mn-oxides in distribution and concentration of REEs, Pb, Zn and Cu. Mineralogical and geochemical evidence such as presence of pyrophyllite, alunite and rutile, enrichment of LREEs relative to HREEs, low values of La+Ce+Y, negative Ce anomaly and strong positive correlations between (LREEs/HREEs)N-LOI and (La/Lu)N-P suggest that the development and evolution of argillic alteration zone in the Jizvan area is affiliated to hypogene processes.
