Economic Geology
Negar Kaboudmehri; Hossein Kouhestani; Mir Ali asghar Mokhtari; Afshin Zohdi
Abstract
The Toryan occurrence is located in the Central Iran zone, 120 km northwest of Zanjan. Pb–Zn mineralization at Toryan occurred as laminated and lens-shaped parallel to lamination of grey sandstone units of the Upper Red Formation. Mineralization often formed around and within the fragments of the ...
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The Toryan occurrence is located in the Central Iran zone, 120 km northwest of Zanjan. Pb–Zn mineralization at Toryan occurred as laminated and lens-shaped parallel to lamination of grey sandstone units of the Upper Red Formation. Mineralization often formed around and within the fragments of the plant fossils, and shows disseminated, replacement, solution seems, intergranoular cement, framboidal, and vein-veinlet textures. At Toryan, ore horizon has 1 m thickness and approximately 350 m length and contains three zones include the red oxidized zone, the bleached zone and the mineralized reduced zone. Galena, sphalerite, pyrite and arsenopyrite are the main ore minerals at Toryan occurrence. Cerussite and goethite are formed during supergene and wethering processes. Comparison of trace elements and REE patterns of barren red and grey host sandstones and mineralized samples indicate that mineralized samples show lower concentrations of trace elements and REE. Based on tectonic setting, sedimentary environment, host rock, presence of plant fossils, geometry, ore texture and mineralogy and alteration, Toryan occurrence can be classified as sediment-hosted Cu deposits of Redbed type, and is comparable with another Redbed type of Cu and Pb–Zn deposits in the Avaj-Zanjan-Tabriz-Khoy belt.
Economic Geology
Fatemeh Naderlou; Mir Ali asghar Mokhtari; Hossein Kouhestani; Ghasem Nabatian
Abstract
North Chargar Cu-Au mineralization located within the Tarom-Hashtjin sub-zone. This area composed of andesite and quartz-andesite lavas alternated with tuffaceouce rocks. The volcanic rocks have calc-alkaline nature and were formed in an active continental margin. Mineralization present as ore-bearing ...
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North Chargar Cu-Au mineralization located within the Tarom-Hashtjin sub-zone. This area composed of andesite and quartz-andesite lavas alternated with tuffaceouce rocks. The volcanic rocks have calc-alkaline nature and were formed in an active continental margin. Mineralization present as ore-bearing quartz vein-veinlets within a silicified zone. Based on mineralogical studies, chalcopyrite and pyrite are the main ore minerals, and malachite, covellite, chalcocite and goethite were formed by supergene processes. Quartz, barite and chlorite present as gangue minerals. Hydrothermal alterations include silicification, chloritization, sericitization and argillic. Ore and gangue minerals show disseminated, vein-veinlet, brecciated, cockade, comb, replacement, relict and open space filling textures. Based on field and microscopic studies, Cu-Au mineralization in the north Chargar can be divided into four stages: 1- the first stage is silicification of volcano-sedimentary host rock along with disseminated pyrite mineralization, 2- the second stage present as chalcopyrite and pyrite-bearing quartz vein-veinlets and hydrothermal breccia cement, 3- the third stage includes barite vein-veinlets crosscutting the previous stages of mineralization, 4- the last stage is related to supergene processes. Geological features, mineralogy and ore structure-textures in the north Chargar Cu-Au occurrence indicate most similarity with base metal epithermal (intermediate sulfidation) deposit type.
Economic Geology
Hossein Bagherpour; Mir Ali Asghar Mokhtari; Hossein Kouhestani; Ghasem Nabatian
Abstract
Qoyjeh Yeylaq volcanic rocks is located approximately in the 120 km southwest of Zanjan, within the Central Iranian zone. The rock units in this area belong to the Cenozoic which consist of mainly Oligo-Miocene volcanic (Basaltic- andesitic lavas) and sedimentary rocks. Based on geochemical classification, ...
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Qoyjeh Yeylaq volcanic rocks is located approximately in the 120 km southwest of Zanjan, within the Central Iranian zone. The rock units in this area belong to the Cenozoic which consist of mainly Oligo-Miocene volcanic (Basaltic- andesitic lavas) and sedimentary rocks. Based on geochemical classification, the mentioned volcanic rocks are basalt, basaltic andesite and andesite in composition, and have calc- alkaline to high-K calc-alkaline affinity. In the primitive mantle normalized spider diagrams, all of the volcanic rocks show similar patterns with enrichment in LILE (Ba, Th, K, Pb) and negative anomalies of HFSE (Nb, Ti). These rocks show LREE enrichment relative to HREE and high ratio of LREE/HREE. Based on tectonomagmatic discrimination diagrams these volcanic rocks were formed in a continental arc setting. Based on geochemical data, it seems that volcanic rocks of the Qoyjeh Yeylaq area were formed from 5-20 % partial melting of a garnet- spinel lherzolite enriched mantle by subduction of Neo-Tethys under the central Iran, within the Orumieh- Dokhtar magmatic arc.
Economic Geology
Ali Rajabzadeh; Hossein Kouhestani; Mir Ali Asghar Mokhtari; Afshin Zohdi
Abstract
In this study, petrography and major and minor elements geochemical data are presented for sandstone layers of the Upper Red Formation (URF) in the Chehrabad Pb-Zn deposit (NW Zanjan) to investigate sandstone composition, tectonic setting and their source rock. In this area, URF has 980 m thickness and ...
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In this study, petrography and major and minor elements geochemical data are presented for sandstone layers of the Upper Red Formation (URF) in the Chehrabad Pb-Zn deposit (NW Zanjan) to investigate sandstone composition, tectonic setting and their source rock. In this area, URF has 980 m thickness and is conformably overlies the Qom Formation limestones. Based on the microscopic studies, these sandstones mainly composed of fine- to coarse-grained clastic fragments including sedimentary and metamorphic rock fragments (45 %), quartz (38 %) and feldspar (17 %). Based on petrographic studies, these sandstones are feldspathic litharenite and litharenite (mainly chertarenite). Based on the main components and major and minor elements geochemical data, the tectonic setting of these sandstones is an active continental margins and foreland basins. These data represent an intermediate to felsic source rock for these sandstones which was affected by the semi-humid to semi-arid climate and a low chemical weathering.
Economic Geology
Amir Naderi; Ghasem Nabatian; Maryam Honarmand; Hossein Kouhestani
Abstract
Halab manganese deposit is located in the Sanandaj- sirjan zone, 100 km southwest of Zanjan. The rock units in the study area include Precambrian Kahar and Jangoutaran marble Formations. Manganese mineralization in the Halab area, occurred as veins and massive in the Jangoutaran marble and minor amount ...
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Halab manganese deposit is located in the Sanandaj- sirjan zone, 100 km southwest of Zanjan. The rock units in the study area include Precambrian Kahar and Jangoutaran marble Formations. Manganese mineralization in the Halab area, occurred as veins and massive in the Jangoutaran marble and minor amount in the schist unit. The main important minerals in the Halab manganese mineralization consist of pyrolusite, psilomelane, manganite and goethite, which calcite and quartz occurred as associated gangue minerals. The ore textures include cloform, vein-veinlets, massive, comb, dogtooth, botryoidal, replacement and relict. Actinolite, carbonate and silicic are the main important alterations in this area. Primitive mantle normalized of the rare earth elements (REE) patterns in the orebody and hydrothermal carbonate samples show that the samples relatively enrichmed in light REE. The analyzed samples show significant negative anomaly in Ce and weak negative anomalies in Eu. Furthermore, the primitive mantle normalized pattern of trace elements in the orebody and hydrothermal carbonate show significant enrichment in Ba, U, La, Pb, Sr and negative anomaly in Rb, Th, Nb, Ce, P, Zr and Ti. The field and microscopic studies as well geochemical evidences suggest that the mineralization formed by hydrothermal fluids. The circulation of meteoric and/or magmatic fluids within the Precambrian units provide the important elements such as Mn, Fe and Ca for mineralization. When the mineralizing fluid contact with reactable rocks, caused the formation of Mn mineralization in the Halab area.
Fariba Asiay Soufiani; Hossein Kouhestani; Amir Morteza Azimzadeh
Abstract
Qarachilar Cu-Mo-Au mineralization is located within the Qaradagh batholite in the Arasbaran metalogenic zone. This area is a part of southern margin of Lesser Caucasus. Qaradagh batholite at the Qarachilar mineralization area composed of granodiorite- quartz monzodiorite (as the main phase and host ...
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Qarachilar Cu-Mo-Au mineralization is located within the Qaradagh batholite in the Arasbaran metalogenic zone. This area is a part of southern margin of Lesser Caucasus. Qaradagh batholite at the Qarachilar mineralization area composed of granodiorite- quartz monzodiorite (as the main phase and host rock of mineralization), diorite, quartz monzonitic stocks, apophyses of porphyritic granite and acidic to intermediate dykes. These intrusions have Upper Eocene- lower Miocene age. All of the mentioned intrusion phases have calc-alkaline to high-K calc-alkaline nature and classified as metaluminous I-type granites. The porphyritic granite apophyses and dykes, and quartz monzonitic stocks have adakitic nature and can be classified as high silica adakites. Chondrite normalized REE patterns in granodiorites- quartz monzodiorites indicate enrichment in LREE and flat trend in MREE and HREE, while porphyritic granites show steep pattern with enrichment in LREE and depletion in HREE. Based on field investigation, geological, petrological, geochemical and tectonomagmatic discrimination diagrams, it can be conclude that granodiorite- quartz monzodiorite phase was formed in active continental margin as a result of Neo-Tethyan ocean subduction beneath the Eurasia. The quartz monzonite stocks and porphyritic granites were formed in a post collisional setting from metasomatized lithospheric mantle wedge.
Economic Geology
Fattaneh Pourmohammad; Hossein Kouhestani; Amir Morteza Azimzadeh; Ghasem Nabatian; Mir Ali Asghar Mokhtari
Abstract
Mianaj Fe ore occurrence is located in the Takab-Angouran-Takht-e-Soleyman metallogenic zone, 100 km southwest of Zanjan. In this area, Fe mineralization occurs as lens-shaped bodies parallel to the foliation of schist and rhyolitic meta-tuff units (equal to Kahar Formation). Based on mineralography, ...
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Mianaj Fe ore occurrence is located in the Takab-Angouran-Takht-e-Soleyman metallogenic zone, 100 km southwest of Zanjan. In this area, Fe mineralization occurs as lens-shaped bodies parallel to the foliation of schist and rhyolitic meta-tuff units (equal to Kahar Formation). Based on mineralography, ore mineral is magnetite, and quartz present as gangue mineral at Mianaj. The ore minerals show disseminated, laminated, banded, massive, vein-veinlet and replacement textures. Three stages of mineralization can be distinguished at Mianaj. The first stage is recognized as stratiform and stratabound lenses, laminated and disseminated crystals of magnetite parallet to the foliation of host rocks. Stage-2 mineralization is recognized by folding of ore bands, σ microfabric and boudinage of magnetite crystals, quartz pressure shadows and surrounding of foliation around magnetite crystals, and recrystallization of quartz and magnetite crystals. Stage-3 is recognized by quartz vein-veinlets that cut previous mineralization stages. Chondrite-nonmineralized REE pattern of host rocks and the mineralized samples indicate that mineralized samples are depleted in REE. This signature indicates mobility of REE by Cl and F-rich oxidized fluids during mineralization processes. Characteristics of Mianaj occurrence are comparable with metamorphosed and deformed volcano-sedimentary type of iron deposits.
Economic Geology
Hossein Kouhestani; Mir Ali Asghar Mokhtari
Abstract
Tashvir ore occurrence, 75 km northeast of Zanjan, is located in the Tarom-Hashtjin subzone. Mineralization occurs as ore-bearing quartz vein-veinlets within the Eocene tuffs and andesitic lavas (equal to Karaj Formation). Ore minerals include chalcocite, chalcopyrite and galena, and quartz, calcite ...
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Tashvir ore occurrence, 75 km northeast of Zanjan, is located in the Tarom-Hashtjin subzone. Mineralization occurs as ore-bearing quartz vein-veinlets within the Eocene tuffs and andesitic lavas (equal to Karaj Formation). Ore minerals include chalcocite, chalcopyrite and galena, and quartz, calcite and chlorite are present as gangue minerals at Tashvir. The ore show vein-veinlets, breccia, disseminated, replacement, relict, colloform, crustiform, dog tooth and plumose textures. Four stages of mineralization can be distinguished at Tashvir. These stages are progressed from quartz- chalcocite- chalcopyrite- galena‒cemented veins and breccias (stage-1), individual or sets of quartz veinlets (stage-2), and vug infill calcite (stage-3) and chlorite (stage-4) vein-veinlets. Hydrothermal alteration consist of silicified, argillic, carbonatic and chloritic. In the outer parts of the mineralization zones, alteration is propylitic. Similar REE patterns of the mineralized veins and the host rocks indicate they are genetically related. Enrichment of ore-forming elements (Ag, Cu, Pb, Zn) in ore zones is specifies leaching of elements from altered host rocks to ore zones. Characteristics of Tashvir ore occurrence are comparable with intermediate-sulfidation style of epithermal base metal (Ag) deposits. Mineralization at Tashvir and other epithermal deposits of the Tarom-Hashtjin subzone took place as a result of hydrothermal activity related to the late Eocene magmatism, and is controlled by fault systems. Therefore, investigation of the altered Eocene volcanic and volcano-sedimentary rocks, especially at the composite place of granitoid intrusions and along the fault structures, became the most favorable locus for epithermal ore bodies at Tarom-Hashtjin subzone.
S. M. Heidari; M. Ghaderi; H. Kouhestani
Abstract
Arabshah gold deposit formed through hydrothermal activity with an age of ~11 Ma (based on zircon U-Pb dating by LA-ICP-MS), in northwestern Iran. This hydrothermal activity is a part of the Urumieh-Dokhtar magmatic arc (UDMA), leading to mineralization in this area, similar to Zarshouran, Aghdarreh ...
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Arabshah gold deposit formed through hydrothermal activity with an age of ~11 Ma (based on zircon U-Pb dating by LA-ICP-MS), in northwestern Iran. This hydrothermal activity is a part of the Urumieh-Dokhtar magmatic arc (UDMA), leading to mineralization in this area, similar to Zarshouran, Aghdarreh and Sarigunay gold deposits. Host rocks are a series of lower Paleozoic sedimentary sequences, cut by calc-alkaline to alkaline (high potassium) dacitic domes. Gold mineralization is mainly observed as vein-veinlets, open space filling, disseminated and brecciation in the deposit. The mineralization in terms of hydrothermal alteration (decalcification, minor argillic, sulfidization, dolomitization and silicification) and mineralization development process is associated with brecciation and deposition of base metal sulfides, iron, arsenic and antimony, similar to deposits associated with geothermal systems (low sulfidation epithermal) in volcanic arcs, but the host rock here is sedimentary. Sulfide minerals in the ore include pyrite, arsenopyrite, orpiment and realgar, stibnite, galena, sphalerite and minor amounts of chalcopyrite. Gold mineralization occurred in the form of released grains of oxidized pyrite, the tiny (invisible) in the sulfide phases such as arsenian pyrite for solid solution. The Arabshah deposit shows characteristic alteration assemblages and ore minerals (As, Sb, Hg, base metals) of epithermal low sulfidation deposits. It has been formed in relation to the mid-upper Miocene, high-level magmatic-hydrothermal activity within an extensional regime at the last stages of the UDMA activity in northwestern Iran.
L. Talebi; M. A. A. Mokhtari; M. Ebrahimi; H. Kouhestani
Abstract
Arpachay Pb-Zn-Cu mineralization occurrence is located in the Takab-Angouran-Takht-e-Soleyman metallogenic zone, 60 km north of Takab. Rock units exposed in the area consist of Oligo-Miocene volcanic, volcano-sedimentary and sedimentary units which are intruded by gabbroic and granodioritic plutons. ...
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Arpachay Pb-Zn-Cu mineralization occurrence is located in the Takab-Angouran-Takht-e-Soleyman metallogenic zone, 60 km north of Takab. Rock units exposed in the area consist of Oligo-Miocene volcanic, volcano-sedimentary and sedimentary units which are intruded by gabbroic and granodioritic plutons. Mineralization occurs as ore-bearing quartz veins hosted by gabbroic pluton in this area. The gabbro shows hetero-granoular texture consisting of plagioclase and clinopyroxene phynocrysts. Geochemical data indicate a calc-alkaline affinity for the gabbroic rocks, associated with active continental margin. These data demonstrate contamination of the parental magma with crustal materials. Based on microscopic studies, ore minerals include galena, sphalerite, chalcopyrite with minor pyrite, and quartz and calcite are present as gangue minerals in the Arpachy occurrence. The ore minerals show vein-veinlets, disseminated, breccia, open space filling, box-work, plumose, cockade and replacement textures. Hydrothermal alteration is restricted to the silicified, sericitic-argillitic and carbonatic altered parts of the ore zones., Alteration occurs as sericitization and calcitization-chloritization (propylitic alteration) of host gabbro. Four stages of mineralization can be distinguished at the Arpachy occurrence. These stages are progressed from brecciation and silicification of host rocks (stage 1) to quartz-chalcopyrite-pyrite‒cemented veins and breccias (stage 2), quartz-galena-sphalerite veins and veinlets (stage 4) and finally individual or sets of late barren quartz-carbonate veins and veinlets (stage 4) in the outer parts of the mineralization zones. REE pattern of the host rocks and the mineralized samples indicate that mineralized samples are depleted in REE. This signature may indicate high water/rock interaction at Arpachay. Geological, mineralogical and textural characteristics of Arpachay occurrence are comparable with intermediate-sulfidation style of epithermal base metal deposits.
S.M Heidari; M Ghaderi; H Kouhestani; M Hosseini
Abstract
The Touzlar epithermal gold deposit formed within the high-K calc-alkaline (shoshonitic) andesitic volcanic units in northwestern Iran. The volcanic complex is in fact a part of magmatism related to the Urumieh-Dokhtar Magmatic Belt crosscutting northeastern rim of the Sanandaj-Sirjan Metamorphic-Magmatic ...
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The Touzlar epithermal gold deposit formed within the high-K calc-alkaline (shoshonitic) andesitic volcanic units in northwestern Iran. The volcanic complex is in fact a part of magmatism related to the Urumieh-Dokhtar Magmatic Belt crosscutting northeastern rim of the Sanandaj-Sirjan Metamorphic-Magmatic Zone. This magmatic system is composed of pyroclastics and lava flow sequences. The volcanic and subvolcanic rocks of the complex constitute a part of the volcano-sedimentary sequence of the Qom Formation, which formed in an extensional regime of basement uplifting and intra-continental basin. Zircon LA-ICP-MS U-Pb dating shows age between 18.4±1.0 and 18.7±0.55 Ma (Lower Miocene) for the volcanism. The hydrothermal alteration types (propylitic, argillic, phyllic, sericitic, advanced argillic and silicification) and evolving mineralization in relation to brecciation and deposition of copper sulfides and sulfosalts imply that the mineralization at Touzlar is similar to that of high sulfidation deposits in volcanic settings. The gold mineralization textures in the Touzlar deposit appear as disseminated, open space filling, veins and veinlets. The main sulfide minerals are pyrite, chalcopyrite, bornite, as well as small amounts of enargite, chalcocite, covellite, digenite, tetrahedrite, galena and sphalerite. The gold in this mineralization occurs as freed from oxidized pyrite grains, also in quartz in hydrothermal breccias as well as solid solution in other minerals such as sulfides and sulfosalts. The main difference in the formation of Touzlar with high sulfidation deposits is in its setting. The formation setting for this mineralization confirms its genesis at low depth and pressure. The deposit formed at the shallow submarine environment of the Qom basin in relation to extensional tectonic regime, while high sulfidation epithermal deposits usually form in subaerial environments related to tensional settings. Structural, host rock type, alteration, paragenesis and Au-Ag (Cu) ore mineralization characteristics of the deposit suggest that Touzlar is most similar to subvolcanic intrusion-related epithermal (high sulfidation) gold deposits formed in intra-arc extensional settings.
H Kouhestani; M.H Ghaderi; M.H Emami; S Meffre; V Kamenetsky; J McPhie; Kh Zaw
Abstract
The Chah Zard Ag-Au deposit, a typical breccia-hosted low- to intermediate-sulfidation epithermal system, is located within late Miocene andesitic to rhyolitic volcanic complex in the central part of the Urumieh-Dokhtar magmatic belt. The orebodies are emplaced in breccia bodies dominantly hosted by ...
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The Chah Zard Ag-Au deposit, a typical breccia-hosted low- to intermediate-sulfidation epithermal system, is located within late Miocene andesitic to rhyolitic volcanic complex in the central part of the Urumieh-Dokhtar magmatic belt. The orebodies are emplaced in breccia bodies dominantly hosted by rhyolite porphyries. Systematic whole-rock geochemical investigations on the volcanic rocks show that both intermediate and felsic rocks are characterized by significant Large Ion Lithophile Elements (LILE) and Light Rare Earth Elements (LREE) enrichment coupled with High Field Strength Elements (HFSE) depletion. These geochemical data indicate subduction-related magmatic arc affinity for the volcanic rocks, and suggest that hornblende fractionation appears to be an important controlling factor on the evolution of mineralized subvolcanic rocks. Although the rhyolite porphyry has relatively high 87Sr/86Sr ratios, the volcanic rocks have similar Sr and Nd isotopic compositions, displaying 87Sr/86Sr range of 0.704910-0.705967 and εNd(i) values of +2.33 to +2.70. These data suggest that the rhyolitic magmas probably represent the final diffetentiates of parental andesitic magmas with minor crustal contamination. The andesitic magmas generated from partial melting of a mixture of an incompatible element depleted anhydrous asthenospheric mantle source and a hydrous LILE and LREE enriched lithospheric mantle source in response to slab-break-off and upwelling of asthenospheric mantle. The rhyolite porphyry is inferred to have supplied heat that drove the convective hydrothermal system at Chah Zard deposit, but also provided some of the fluid sources responsible for the development of the Chah Zard epithermal system.
Majid Ghaderi; H. Kouhestani; M. H. Emami; K. Zaw
Abstract
The breccia-hosted epithermal Ag-Au deposit of Chah Zard is located within an andesitic to rhyolitic volcanic complex in the central part of the Urumieh-Dokhtar magmatic belt. At this location, magmatic and hydrothermal activity was associated with local extensional tectonics, formed in the Dehshir-Baft ...
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The breccia-hosted epithermal Ag-Au deposit of Chah Zard is located within an andesitic to rhyolitic volcanic complex in the central part of the Urumieh-Dokhtar magmatic belt. At this location, magmatic and hydrothermal activity was associated with local extensional tectonics, formed in the Dehshir-Baft strike-slip fault system. The host rocks of the volcanic complex consist of Eocene sedimentary and volcanic rocks covered by Miocene sedimentary rocks. LA-ICP-MS U–Pb zircon geochronology yields ages between 6.36±0.14 and 6.19±0.24 Ma, and a mean age of 6.23±0.16 Ma for magmatic activity at Chah Zard. Breccias and veins were formed during and after the waning stages of strong explosive eruption of magmatic-hydrothermal and phreatomagmatic brecciation events due to shallow emplacement of the rhyolite porphyry. Detailed systematic mapping leads to the recognition of three distinct breccia bodies: the volcaniclastic breccia with a dominantly clastic matrix, the gray polymict breccia with a greater proportion of hydrothermal cements, and the mono-polymict breccia with argillic groundmass matrix. The polymictic breccias generated bulk-mineable ore, whereas the volcaniclastic breccia is relatively impermeable and largely barren. Variable hydrothermal alteration occurs in outcrops, covering about 9 km2 at Chah Zard. Hydrothermal alteration assemblages are zoned around the breccias and veins, consisting of secondary quartz, illite, pyrite, adularia, chlorite, various carbonate minerals, and minor K-feldspar. Iron oxide-hydroxide, jarosite, gypsum, kaolinite, halloysite and rare alunite are the supergene alteration minerals replacing primary minerals, and filling the fractures and vugs. Precious metals occur with sulfide and sulfosalt minerals as disseminations in the veins and breccia cement. There is a progression from pyrite-dominated (stage 1) to pyrite-base metal sulfide and sulfosalt-dominated (stages 2 and 3) to base metal sulfide-dominated (stage 4) breccias and veins. Deposition of gangue minerals progressed from illite-quartz to quartz-adularia, carbonate and finally gypsum-dominated assemblages. Free gold occurs in stages 2 and 4, principally as intergrown with pyrite, quartz, chalcopyrite, galena, sphalerite, and Ag-rich tennantite-tetrahedrite; and also as inclusions in pyrite. The U-Pb zircon age of 6.19±0.24 Ma for emplacement of the rhyolitic magmas represents the maximum age of mineralization at Chah Zard. It may indicate that there was a previously unrecognized mineralization event in Urumieh-Dokhtar at this time.
